[CH3COH].+, the central intermediate in the isomerization-dissociation reactions of ionized vinyl alcohol

Yitzhak Apeloig; Miriam Karni; Bernhard Ciommer; Gisbert Depke; Gernot Frenking; Stefan Meyn; Jochen Schmidt; Helmut Schwarz

[CH₃COH]^.+, the central intermediate in the isomerization-dissociation reactions of ionized vinyl alcohol

Yitzhak Apeloig, Miriam Karni, Bernhard Ciommer, Gisbert Depke, Gernot Frenking, Stefan Meyn, Jochen Schmidt, Helmut Schwarz

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

In complete agreement with experimental results ab initio molecular orbital calculations predict that ionized hydroxy(methyl)carbene, [CH ₃COH]⁺, does not only exist as a stable C ₂H₄O^.- isomer but also serves as the key intermediate in the isomerization-dissociation processes of the cation radical of gaseous vinyl alcohol.

Original language	English
Pages (from-to)	1497-1499
Number of pages	3
Journal	Chemical Communications
Issue number	24
State	Published - 1983
Externally published	Yes

Cite this

@article{bdf6e613c0df444a968111b89a87cb60,

title = "[CH3COH].+, the central intermediate in the isomerization-dissociation reactions of ionized vinyl alcohol",

abstract = "In complete agreement with experimental results ab initio molecular orbital calculations predict that ionized hydroxy(methyl)carbene, [CH 3COH]+, does not only exist as a stable C 2H4O.- isomer but also serves as the key intermediate in the isomerization-dissociation processes of the cation radical of gaseous vinyl alcohol.",

author = "Yitzhak Apeloig and Miriam Karni and Bernhard Ciommer and Gisbert Depke and Gernot Frenking and Stefan Meyn and Jochen Schmidt and Helmut Schwarz",

year = "1983",

language = "英语",

pages = "1497--1499",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "24",

}

TY - JOUR

T1 - [CH3COH].+, the central intermediate in the isomerization-dissociation reactions of ionized vinyl alcohol

AU - Apeloig, Yitzhak

AU - Karni, Miriam

AU - Ciommer, Bernhard

AU - Depke, Gisbert

AU - Frenking, Gernot

AU - Meyn, Stefan

AU - Schmidt, Jochen

AU - Schwarz, Helmut

PY - 1983

Y1 - 1983

N2 - In complete agreement with experimental results ab initio molecular orbital calculations predict that ionized hydroxy(methyl)carbene, [CH 3COH]+, does not only exist as a stable C 2H4O.- isomer but also serves as the key intermediate in the isomerization-dissociation processes of the cation radical of gaseous vinyl alcohol.

AB - In complete agreement with experimental results ab initio molecular orbital calculations predict that ionized hydroxy(methyl)carbene, [CH 3COH]+, does not only exist as a stable C 2H4O.- isomer but also serves as the key intermediate in the isomerization-dissociation processes of the cation radical of gaseous vinyl alcohol.

UR - http://www.scopus.com/inward/record.url?scp=37049093923&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:37049093923

SN - 0022-4936

SP - 1497

EP - 1499

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

[CH₃COH]^.+, the central intermediate in the isomerization-dissociation reactions of ionized vinyl alcohol

Abstract

Other files and links

Fingerprint

Cite this