C(NHC)2: Divalent carbon(0) compounds with N-heterocyclic carbene ligands - Theoretical evidence for a class of molecules with promising chemical properties

Ralf Tonner; Gernot Frenking

doi:10.1002/anie.200701632

C(NHC)₂: Divalent carbon(0) compounds with N-heterocyclic carbene ligands - Theoretical evidence for a class of molecules with promising chemical properties

Ralf Tonner, Gernot Frenking

University of Marburg

Research output: Contribution to journal › Article › peer-review

341 Scopus citations

Abstract

(Chemical Equation Presented) Future targets: Quantum-chemical calculations predict that the experimentally still unknown carbodicarbenes C(NHC) ₂ (NHC = N-heterocyclic carbene; see picture for example) are a synthetically accessible class of divalent carbon(0) compounds which are very strong nucleophiles and bases that may be useful ligands for transition-metal complexes.

Original language	English
Pages (from-to)	8695-8698
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	45
DOIs	https://doi.org/10.1002/anie.200701632
State	Published - 2007
Externally published	Yes

Keywords

Carbodiphosphoranes
Density functional calculations
Divalent carbon(0)
Donor-acceptor systems
Nucleophiles

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10.1002/anie.200701632

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abstract = "(Chemical Equation Presented) Future targets: Quantum-chemical calculations predict that the experimentally still unknown carbodicarbenes C(NHC) 2 (NHC = N-heterocyclic carbene; see picture for example) are a synthetically accessible class of divalent carbon(0) compounds which are very strong nucleophiles and bases that may be useful ligands for transition-metal complexes.",

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KW - Carbodiphosphoranes

KW - Density functional calculations

KW - Divalent carbon(0)

KW - Donor-acceptor systems

KW - Nucleophiles

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C(NHC)₂: Divalent carbon(0) compounds with N-heterocyclic carbene ligands - Theoretical evidence for a class of molecules with promising chemical properties

Abstract

Keywords

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