Cobalt-catalyzed cross-coupling of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium reagents

Yan Ying Cui; Jin He Na; Meng Meng Guo; Jie Ying Huang; Xue Qiang Chu; Weidong Rao; Zhi Liang Shen

doi:10.1016/j.tetlet.2022.153662

Cobalt-catalyzed cross-coupling of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium reagents

Yan Ying Cui, Jin He Na, Meng Meng Guo, Jie Ying Huang, Xue Qiang Chu, Weidong Rao, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Cobalt-catalyzed cross-couplings of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium halides proceeded efficiently with the aid of cobalt(II) catalyst and copper(I) salt in tetrahydrofuran at ambient temperature, producing the desired 4-arylated pyridine, quinoline, and quinoxaline in modest to good yields.

Original language	English
Article number	153662
Journal	Tetrahedron Letters
Volume	92
DOIs	https://doi.org/10.1016/j.tetlet.2022.153662
State	Published - 2 Mar 2022

Keywords

Arylmagnesium reagent
Cobalt catalysis
Cross-coupling
Nitrogen-containing heterocyclic phosphonium salts
Pyridine

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10.1016/j.tetlet.2022.153662

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title = "Cobalt-catalyzed cross-coupling of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium reagents",

abstract = "Cobalt-catalyzed cross-couplings of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium halides proceeded efficiently with the aid of cobalt(II) catalyst and copper(I) salt in tetrahydrofuran at ambient temperature, producing the desired 4-arylated pyridine, quinoline, and quinoxaline in modest to good yields.",

keywords = "Arylmagnesium reagent, Cobalt catalysis, Cross-coupling, Nitrogen-containing heterocyclic phosphonium salts, Pyridine",

author = "Cui, {Yan Ying} and Na, {Jin He} and Guo, {Meng Meng} and Huang, {Jie Ying} and Chu, {Xue Qiang} and Weidong Rao and Shen, {Zhi Liang}",

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doi = "10.1016/j.tetlet.2022.153662",

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TY - JOUR

T1 - Cobalt-catalyzed cross-coupling of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium reagents

AU - Cui, Yan Ying

AU - Na, Jin He

AU - Guo, Meng Meng

AU - Huang, Jie Ying

AU - Chu, Xue Qiang

AU - Rao, Weidong

AU - Shen, Zhi Liang

PY - 2022/3/2

Y1 - 2022/3/2

N2 - Cobalt-catalyzed cross-couplings of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium halides proceeded efficiently with the aid of cobalt(II) catalyst and copper(I) salt in tetrahydrofuran at ambient temperature, producing the desired 4-arylated pyridine, quinoline, and quinoxaline in modest to good yields.

AB - Cobalt-catalyzed cross-couplings of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium halides proceeded efficiently with the aid of cobalt(II) catalyst and copper(I) salt in tetrahydrofuran at ambient temperature, producing the desired 4-arylated pyridine, quinoline, and quinoxaline in modest to good yields.

KW - Arylmagnesium reagent

KW - Cobalt catalysis

KW - Cross-coupling

KW - Nitrogen-containing heterocyclic phosphonium salts

KW - Pyridine

UR - http://www.scopus.com/inward/record.url?scp=85124461993&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2022.153662

DO - 10.1016/j.tetlet.2022.153662

M3 - 文章

AN - SCOPUS:85124461993

SN - 0040-4039

VL - 92

JO - Tetrahedron Letters

JF - Tetrahedron Letters

M1 - 153662

ER -

Cobalt-catalyzed cross-coupling of nitrogen-containing heterocyclic phosphonium salts with arylmagnesium reagents

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Keywords

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