Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

Peng Wang; Xuan Di Song; Bing Zhi Chen; Weidong Rao; Zhi Liang Shen

doi:10.1016/j.catcom.2019.105824

Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

Peng Wang, Xuan Di Song, Bing Zhi Chen, Weidong Rao, Zhi Liang Shen

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.

Original language	English
Article number	105824
Journal	Catalysis Communications
Volume	132
DOIs	https://doi.org/10.1016/j.catcom.2019.105824
State	Published - Dec 2019

Keywords

Alkylindium reagent
Cobalt catalysis
Cross-coupling reaction
Functional group tolerance
Indium
Palladium

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10.1016/j.catcom.2019.105824

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title = "Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides",

abstract = "The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.",

keywords = "Alkylindium reagent, Cobalt catalysis, Cross-coupling reaction, Functional group tolerance, Indium, Palladium",

author = "Peng Wang and Song, {Xuan Di} and Chen, {Bing Zhi} and Weidong Rao and Shen, {Zhi Liang}",

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year = "2019",

month = dec,

doi = "10.1016/j.catcom.2019.105824",

language = "英语",

volume = "132",

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T1 - Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

AU - Wang, Peng

AU - Song, Xuan Di

AU - Chen, Bing Zhi

AU - Rao, Weidong

AU - Shen, Zhi Liang

PY - 2019/12

Y1 - 2019/12

N2 - The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.

AB - The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.

KW - Alkylindium reagent

KW - Cobalt catalysis

KW - Cross-coupling reaction

KW - Functional group tolerance

KW - Indium

KW - Palladium

UR - http://www.scopus.com/inward/record.url?scp=85073146335&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2019.105824

DO - 10.1016/j.catcom.2019.105824

M3 - 文章

AN - SCOPUS:85073146335

SN - 1566-7367

VL - 132

JO - Catalysis Communications

JF - Catalysis Communications

M1 - 105824

ER -

Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

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Keywords

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