Comment on "disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations"

Gernot Frenking; Andreas Krapp; Shigeru Nagase; Nozomi Takagi; Akira Sekiguchi

doi:10.1002/cphc.200500689

Comment on "disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations"

Gernot Frenking, Andreas Krapp, Shigeru Nagase, Nozomi Takagi, Akira Sekiguchi

Research output: Contribution to journal › Review article › peer-review

29 Scopus citations

Abstract

(Figure presented) Bond order of a silicon-silicon bond (1): The statement that the recently synthesized compound RSi-SiR (1) (R=Si[C(SiMe ₃)₃]₂CHMe₂) has rather a double than a triple bond is challenged. Arguments are given which support the interpretation of the bonding situation in terms of two donor-acceptor bonds which are enhanced by one π bond (see picture).

Original language	English
Pages (from-to)	799-800
Number of pages	2
Journal	ChemPhysChem
Volume	7
Issue number	4
DOIs	https://doi.org/10.1002/cphc.200500689
State	Published - 10 Apr 2006
Externally published	Yes

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abstract = "(Figure presented) Bond order of a silicon-silicon bond (1): The statement that the recently synthesized compound RSi-SiR (1) (R=Si[C(SiMe 3)3]2CHMe2) has rather a double than a triple bond is challenged. Arguments are given which support the interpretation of the bonding situation in terms of two donor-acceptor bonds which are enhanced by one π bond (see picture).",

author = "Gernot Frenking and Andreas Krapp and Shigeru Nagase and Nozomi Takagi and Akira Sekiguchi",

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T1 - Comment on "disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations"

AU - Frenking, Gernot

AU - Krapp, Andreas

AU - Nagase, Shigeru

AU - Takagi, Nozomi

AU - Sekiguchi, Akira

PY - 2006/4/10

Y1 - 2006/4/10

N2 - (Figure presented) Bond order of a silicon-silicon bond (1): The statement that the recently synthesized compound RSi-SiR (1) (R=Si[C(SiMe 3)3]2CHMe2) has rather a double than a triple bond is challenged. Arguments are given which support the interpretation of the bonding situation in terms of two donor-acceptor bonds which are enhanced by one π bond (see picture).

AB - (Figure presented) Bond order of a silicon-silicon bond (1): The statement that the recently synthesized compound RSi-SiR (1) (R=Si[C(SiMe 3)3]2CHMe2) has rather a double than a triple bond is challenged. Arguments are given which support the interpretation of the bonding situation in terms of two donor-acceptor bonds which are enhanced by one π bond (see picture).

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DO - 10.1002/cphc.200500689

M3 - 文献综述

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JF - ChemPhysChem

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Comment on "disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations"

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