Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814

Sudip Pan; Gernot Frenking

doi:10.1039/c9cp05951b

Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814

Sudip Pan, Gernot Frenking

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

We challenge the statement of Koch et al. that the M → CO charge transfer and the decrease of the CO stretching frequency in metal carbonyl complexes do not depend on the metal d orbitals. The approach of the authors is severely flawed and leads to misleading conclusions.

Original language	English
Pages (from-to)	5377-5379
Number of pages	3
Journal	Physical Chemistry Chemical Physics
Volume	22
Issue number	9
DOIs	https://doi.org/10.1039/c9cp05951b
State	Published - 7 Mar 2020

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Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814. / Pan, Sudip; Frenking, Gernot.
In: Physical Chemistry Chemical Physics, Vol. 22, No. 9, 07.03.2020, p. 5377-5379.

Research output: Contribution to journal › Article › peer-review

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AB - We challenge the statement of Koch et al. that the M → CO charge transfer and the decrease of the CO stretching frequency in metal carbonyl complexes do not depend on the metal d orbitals. The approach of the authors is severely flawed and leads to misleading conclusions.

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Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814

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