Comments on "Homoleptical silver(I) acetylene complexes"

Andreas Krapp, Gernot Frenking

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Abstract

In a recent publication, Krossing, Scherer, and co-workers reported interesting experimental results for homoleptic AgI acetylene complexes. In this Correspondence the interpretation of the X-ray analysis and the claim of "pseudo-gas-phase conditions" in the solid state are questioned.

Original languageEnglish
Pages (from-to)7796-7797
Number of pages2
JournalAngewandte Chemie - International Edition
Volume47
Issue number41
DOIs
StatePublished - 29 Sep 2008
Externally publishedYes

Keywords

  • Ab initio calculations
  • Alkynes
  • Silver
  • Structure elucidation
  • Weakly coordinating anions

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