TY - JOUR
T1 - Construction of high-performance NiCe-MOF derived structured catalyst for steam reforming of biomass tar model compound
AU - Zhang, Siqian
AU - Xiang, Xiaan
AU - Shen, Zhangfeng
AU - Wang, Yinfeng
AU - Li, Xi
AU - Zou, Xuhui
AU - Xu, Haiyang
AU - Cao, Yongyong
AU - Chen, Haijun
AU - Wang, Yangang
N1 - Publisher Copyright:
© 2022 Hydrogen Energy Publications LLC
PY - 2022/9/1
Y1 - 2022/9/1
N2 - High-performance and inexpensive catalysts play a large role in effective removal of biomass tar produced during biomass gasification. In this study, raw wood, with long, through, but distorted channels and a low tortuosity, was selected as a support. A layered NiCe-metal organic framework (NiCe-MOF) was grown in-situ on the surface of raw wood microchannels by using abundant surface hydroxide groups. Then, this catalyst was carbonized at 600 °C in a N2 atmosphere to obtain NiCe-MOF derived catalyst/wood carbon (NiCe-MDC/WC), which was selected as a structured reactor for the steam reforming of biomass tar. NiCe-MDC/WC achieved an excellent conversion rate of approximately 99% for toluene and a high catalytic stability of 48 h at low temperature of 550 °C. Moreover, NiCe-MDC/WC showed higher catalytic performance than Ni-MDC/WC (∼79%), crushed-NiCe-MDC/WC (∼94%), and Ni/WC (∼75%) in stability tests. These excellent results were assumed to be derived from the multilevel structure obtained from wood carbon microchannels and secondary layered MOF channels, appropriate metal-support interactions, and the presence of Ce, which could improve the dispersion of active sites and mass transfer efficiency and inhibit coke formation. Thus, such Ni-based MOF-derived structured reactors are promising for tar conversion and useful syngas production.
AB - High-performance and inexpensive catalysts play a large role in effective removal of biomass tar produced during biomass gasification. In this study, raw wood, with long, through, but distorted channels and a low tortuosity, was selected as a support. A layered NiCe-metal organic framework (NiCe-MOF) was grown in-situ on the surface of raw wood microchannels by using abundant surface hydroxide groups. Then, this catalyst was carbonized at 600 °C in a N2 atmosphere to obtain NiCe-MOF derived catalyst/wood carbon (NiCe-MDC/WC), which was selected as a structured reactor for the steam reforming of biomass tar. NiCe-MDC/WC achieved an excellent conversion rate of approximately 99% for toluene and a high catalytic stability of 48 h at low temperature of 550 °C. Moreover, NiCe-MDC/WC showed higher catalytic performance than Ni-MDC/WC (∼79%), crushed-NiCe-MDC/WC (∼94%), and Ni/WC (∼75%) in stability tests. These excellent results were assumed to be derived from the multilevel structure obtained from wood carbon microchannels and secondary layered MOF channels, appropriate metal-support interactions, and the presence of Ce, which could improve the dispersion of active sites and mass transfer efficiency and inhibit coke formation. Thus, such Ni-based MOF-derived structured reactors are promising for tar conversion and useful syngas production.
KW - Coke resistance
KW - In-situ growth
KW - Layered NiCe-MOF
KW - Monolithic wood carbon
KW - Tar steam reforming
UR - http://www.scopus.com/inward/record.url?scp=85135800984&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2022.07.097
DO - 10.1016/j.ijhydene.2022.07.097
M3 - 文章
AN - SCOPUS:85135800984
SN - 0360-3199
VL - 47
SP - 32004
EP - 32014
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 75
ER -
