Continuous flow cationic polymerizations

Huiyue Wang; Zhao Jin; Xin Hu; Qiao Jin; Songwei Tan; Ali Reza Mahdavian; Ning Zhu; Kai Guo

doi:10.1016/j.cej.2021.132791

Continuous flow cationic polymerizations

Huiyue Wang, Zhao Jin, Xin Hu, Qiao Jin, Songwei Tan, Ali Reza Mahdavian, Ning Zhu, Kai Guo

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Research output: Contribution to journal › Review article › peer-review

21 Scopus citations

Abstract

As the typical highly exothermic polymerization, cationic polymerization suffers from harsh reaction conditions and poor control of polymerizations. The combination of microreactor and cation pool method or carbocation stabilization achieves improved living cationic polymerizations under mild conditions. In this review, not only cationic addition polymerizations of vinyl monomers (vinyl ether, isobutene, and diisopropenylbenzen) but also cationic ring-opening polymerizations of cyclic monomer (oxazoline) will be highlighted in the context of microreactor-based flow chemistry. Challenges and opportunities are proposed with the aim to promote the development of cationic polymerization in both academia and industry.

Original language	English
Article number	132791
Journal	Chemical Engineering Journal
Volume	430
DOIs	https://doi.org/10.1016/j.cej.2021.132791
State	Published - 15 Feb 2022

Keywords

Addition polymerization
Cationic polymerization
Continuous flow
Ring-opening polymerization

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10.1016/j.cej.2021.132791

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title = "Continuous flow cationic polymerizations",

abstract = "As the typical highly exothermic polymerization, cationic polymerization suffers from harsh reaction conditions and poor control of polymerizations. The combination of microreactor and cation pool method or carbocation stabilization achieves improved living cationic polymerizations under mild conditions. In this review, not only cationic addition polymerizations of vinyl monomers (vinyl ether, isobutene, and diisopropenylbenzen) but also cationic ring-opening polymerizations of cyclic monomer (oxazoline) will be highlighted in the context of microreactor-based flow chemistry. Challenges and opportunities are proposed with the aim to promote the development of cationic polymerization in both academia and industry.",

keywords = "Addition polymerization, Cationic polymerization, Continuous flow, Ring-opening polymerization",

author = "Huiyue Wang and Zhao Jin and Xin Hu and Qiao Jin and Songwei Tan and {Reza Mahdavian}, Ali and Ning Zhu and Kai Guo",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2022",

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doi = "10.1016/j.cej.2021.132791",

language = "英语",

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TY - JOUR

T1 - Continuous flow cationic polymerizations

AU - Wang, Huiyue

AU - Jin, Zhao

AU - Hu, Xin

AU - Jin, Qiao

AU - Tan, Songwei

AU - Reza Mahdavian, Ali

AU - Zhu, Ning

AU - Guo, Kai

PY - 2022/2/15

Y1 - 2022/2/15

N2 - As the typical highly exothermic polymerization, cationic polymerization suffers from harsh reaction conditions and poor control of polymerizations. The combination of microreactor and cation pool method or carbocation stabilization achieves improved living cationic polymerizations under mild conditions. In this review, not only cationic addition polymerizations of vinyl monomers (vinyl ether, isobutene, and diisopropenylbenzen) but also cationic ring-opening polymerizations of cyclic monomer (oxazoline) will be highlighted in the context of microreactor-based flow chemistry. Challenges and opportunities are proposed with the aim to promote the development of cationic polymerization in both academia and industry.

AB - As the typical highly exothermic polymerization, cationic polymerization suffers from harsh reaction conditions and poor control of polymerizations. The combination of microreactor and cation pool method or carbocation stabilization achieves improved living cationic polymerizations under mild conditions. In this review, not only cationic addition polymerizations of vinyl monomers (vinyl ether, isobutene, and diisopropenylbenzen) but also cationic ring-opening polymerizations of cyclic monomer (oxazoline) will be highlighted in the context of microreactor-based flow chemistry. Challenges and opportunities are proposed with the aim to promote the development of cationic polymerization in both academia and industry.

KW - Addition polymerization

KW - Cationic polymerization

KW - Continuous flow

KW - Ring-opening polymerization

UR - http://www.scopus.com/inward/record.url?scp=85116910413&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2021.132791

DO - 10.1016/j.cej.2021.132791

M3 - 文献综述

AN - SCOPUS:85116910413

SN - 1385-8947

VL - 430

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 132791

ER -

Continuous flow cationic polymerizations

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Keywords

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