CO2/N2 separation performance of supported ionic liquid membrane fabricated by [Choline][Pro]/ RTILs

Yankai Zhao; Tengteng Fan; Wenlong Xie; Suoying Zhang; Chang Liu; Xin Feng; Xiaohua Lu

doi:10.11949/j.issn.0438-1157.20170187

CO₂/N₂ separation performance of supported ionic liquid membrane fabricated by [Choline][Pro]/ RTILs

Yankai Zhao, Tengteng Fan, Wenlong Xie, Suoying Zhang, Chang Liu, Xin Feng, Xiaohua Lu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Three mixed ionic liquids ([Choline][Pro]/[EMIm][N(CN)₂], [Choline][Pro]/[bmim][PF₆] and [Choline][Pro]/[HMIm][NTf₂]) were prepared by mixing room temperature ionic liquids (RTILs) with [Choline][Pro]. They were used to prepare SILMs by the impregnation method. Effects of operating temperature, pressure, type and content of RTILs on CO₂/N₂ separation performance of SILMs were investigated. The results showed that the CO₂ permeability of the SILMs changed between 343.3-1936.9 barrer and CO₂/N₂ selectivity was in range of 10.3-34.8. Non-equilibrium thermodynamics was used to analyze CO₂ transport mechanism in SILMs. The overall resistance showed a trend from decline to rise by increasing the proportion of [HMIm][NTf₂] in the mixed ILs, which was in accordance with CO₂ permeability in SILMs.

Original language	English
Pages (from-to)	2771-2780
Number of pages	10
Journal	Huagong Xuebao/CIESC Journal
Volume	68
Issue number	7
DOIs	https://doi.org/10.11949/j.issn.0438-1157.20170187
State	Published - 1 Jul 2017

Keywords

CO
Ionic liquids
SILMs
Separation
[Choline][Pro]

Access to Document

10.11949/j.issn.0438-1157.20170187

Cite this

@article{47f27065761647dbbbc2d12e31d16b6f,

title = "CO2/N2 separation performance of supported ionic liquid membrane fabricated by [Choline][Pro]/ RTILs",

abstract = "Three mixed ionic liquids ([Choline][Pro]/[EMIm][N(CN)2], [Choline][Pro]/[bmim][PF6] and [Choline][Pro]/[HMIm][NTf2]) were prepared by mixing room temperature ionic liquids (RTILs) with [Choline][Pro]. They were used to prepare SILMs by the impregnation method. Effects of operating temperature, pressure, type and content of RTILs on CO2/N2 separation performance of SILMs were investigated. The results showed that the CO2 permeability of the SILMs changed between 343.3-1936.9 barrer and CO2/N2 selectivity was in range of 10.3-34.8. Non-equilibrium thermodynamics was used to analyze CO2 transport mechanism in SILMs. The overall resistance showed a trend from decline to rise by increasing the proportion of [HMIm][NTf2] in the mixed ILs, which was in accordance with CO2 permeability in SILMs.",

keywords = "CO, Ionic liquids, SILMs, Separation, [Choline][Pro]",

author = "Yankai Zhao and Tengteng Fan and Wenlong Xie and Suoying Zhang and Chang Liu and Xin Feng and Xiaohua Lu",

year = "2017",

month = jul,

day = "1",

doi = "10.11949/j.issn.0438-1157.20170187",

language = "英语",

volume = "68",

pages = "2771--2780",

journal = "Huagong Xuebao/CIESC Journal",

issn = "0438-1157",

publisher = "Materials China",

number = "7",

}

TY - JOUR

T1 - CO2/N2 separation performance of supported ionic liquid membrane fabricated by [Choline][Pro]/ RTILs

AU - Zhao, Yankai

AU - Fan, Tengteng

AU - Xie, Wenlong

AU - Zhang, Suoying

AU - Liu, Chang

AU - Feng, Xin

AU - Lu, Xiaohua

PY - 2017/7/1

Y1 - 2017/7/1

N2 - Three mixed ionic liquids ([Choline][Pro]/[EMIm][N(CN)2], [Choline][Pro]/[bmim][PF6] and [Choline][Pro]/[HMIm][NTf2]) were prepared by mixing room temperature ionic liquids (RTILs) with [Choline][Pro]. They were used to prepare SILMs by the impregnation method. Effects of operating temperature, pressure, type and content of RTILs on CO2/N2 separation performance of SILMs were investigated. The results showed that the CO2 permeability of the SILMs changed between 343.3-1936.9 barrer and CO2/N2 selectivity was in range of 10.3-34.8. Non-equilibrium thermodynamics was used to analyze CO2 transport mechanism in SILMs. The overall resistance showed a trend from decline to rise by increasing the proportion of [HMIm][NTf2] in the mixed ILs, which was in accordance with CO2 permeability in SILMs.

AB - Three mixed ionic liquids ([Choline][Pro]/[EMIm][N(CN)2], [Choline][Pro]/[bmim][PF6] and [Choline][Pro]/[HMIm][NTf2]) were prepared by mixing room temperature ionic liquids (RTILs) with [Choline][Pro]. They were used to prepare SILMs by the impregnation method. Effects of operating temperature, pressure, type and content of RTILs on CO2/N2 separation performance of SILMs were investigated. The results showed that the CO2 permeability of the SILMs changed between 343.3-1936.9 barrer and CO2/N2 selectivity was in range of 10.3-34.8. Non-equilibrium thermodynamics was used to analyze CO2 transport mechanism in SILMs. The overall resistance showed a trend from decline to rise by increasing the proportion of [HMIm][NTf2] in the mixed ILs, which was in accordance with CO2 permeability in SILMs.

KW - CO

KW - Ionic liquids

KW - SILMs

KW - Separation

KW - [Choline][Pro]

UR - http://www.scopus.com/inward/record.url?scp=85092429025&partnerID=8YFLogxK

U2 - 10.11949/j.issn.0438-1157.20170187

DO - 10.11949/j.issn.0438-1157.20170187

M3 - 文章

AN - SCOPUS:85092429025

SN - 0438-1157

VL - 68

SP - 2771

EP - 2780

JO - Huagong Xuebao/CIESC Journal

JF - Huagong Xuebao/CIESC Journal

IS - 7

ER -

CO₂/N₂ separation performance of supported ionic liquid membrane fabricated by [Choline][Pro]/ RTILs

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this