TY - JOUR
T1 - Creative Construction of a Series of Chiral 3D Indium-Organic Frameworks with a umy Topology
AU - He, Xin
AU - Wang, Xin
AU - Xiao, Tianyu
AU - Zhang, Shunlin
AU - Zhu, Dunru
N1 - Publisher Copyright:
© 2020 American Chemical Society.
PY - 2021/1/4
Y1 - 2021/1/4
N2 - Using 2,2′-R2-biphenyl-4,4′-dicarboxylic acid to bind with a cis-[InO4(μ2-OH)2] octahedron, three novel chiral 3D indium-organic frameworks, [In(μ2-OH)L] [1, L1, R = N(CH3)2; 2, L2, R = OCH3; 3, L3, R = CH3], have been hydrothermally synthesized without chiral reagents. Crystal structure analyses reveal that 1-3 show an unprecedented 4-connected umy topology with the Schläfli symbol (42·64). 1 exhibits high water stability and good sorption selectivity of CO2 over N2, while 3 displays high C2H2, C2H4, and C2H6 uptake capacity at 273 K.
AB - Using 2,2′-R2-biphenyl-4,4′-dicarboxylic acid to bind with a cis-[InO4(μ2-OH)2] octahedron, three novel chiral 3D indium-organic frameworks, [In(μ2-OH)L] [1, L1, R = N(CH3)2; 2, L2, R = OCH3; 3, L3, R = CH3], have been hydrothermally synthesized without chiral reagents. Crystal structure analyses reveal that 1-3 show an unprecedented 4-connected umy topology with the Schläfli symbol (42·64). 1 exhibits high water stability and good sorption selectivity of CO2 over N2, while 3 displays high C2H2, C2H4, and C2H6 uptake capacity at 273 K.
UR - http://www.scopus.com/inward/record.url?scp=85098979619&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.0c02913
DO - 10.1021/acs.inorgchem.0c02913
M3 - 文章
C2 - 33307672
AN - SCOPUS:85098979619
SN - 0020-1669
VL - 60
SP - 9
EP - 13
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 1
ER -