Crystal and molecular structure of a novel complex [Mn(MOBPT)(H2O)2(NCS)2] (MOBPT = 4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)- 1,2,4-triazole)

Dunru Zhu; Yan Xu; Yuhua Mei; Yujun Shi; Chao Tu; Xiaozeng You

doi:10.1016/S0022-2860(00)00728-6

Crystal and molecular structure of a novel complex [Mn(MOBPT)(H₂O)₂(NCS)₂] (MOBPT = 4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)- 1,2,4-triazole)

Dunru Zhu, Yan Xu, Yuhua Mei, Yujun Shi, Chao Tu, Xiaozeng You

Nanjing University

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

The molecular structure of a novel manganese(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) has been determined by X-ray analysis, FT-IR and by ESI-MS spectroscopy. The manganese atom is in a distorted octahedral environment. Bidentate chelating ligand (MOBPT) and two cis-oriented thiocyanate anions coordinate to the metal center equatorially and two water molecules coordinate axially. MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. The molecules are stabilized by intermolecular hydrogen bonds in the crystal lattice. Magnetic measurements show that the complex is high-spin species in the 75-300 K range.

Original language	English
Pages (from-to)	119-125
Number of pages	7
Journal	Journal of Molecular Structure
Volume	559
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-2860(00)00728-6
State	Published - 7 Jan 2001
Externally published	Yes

Keywords

Crystal structure
ESI-MS spectra
FT-IR
Manganese(II) complex
Triazole

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10.1016/S0022-2860(00)00728-6

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@article{cb53711708fb4899ba1e8e56840beb22,

title = "Crystal and molecular structure of a novel complex [Mn(MOBPT)(H2O)2(NCS)2] (MOBPT = 4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)- 1,2,4-triazole)",

abstract = "The molecular structure of a novel manganese(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) has been determined by X-ray analysis, FT-IR and by ESI-MS spectroscopy. The manganese atom is in a distorted octahedral environment. Bidentate chelating ligand (MOBPT) and two cis-oriented thiocyanate anions coordinate to the metal center equatorially and two water molecules coordinate axially. MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. The molecules are stabilized by intermolecular hydrogen bonds in the crystal lattice. Magnetic measurements show that the complex is high-spin species in the 75-300 K range.",

keywords = "Crystal structure, ESI-MS spectra, FT-IR, Manganese(II) complex, Triazole",

author = "Dunru Zhu and Yan Xu and Yuhua Mei and Yujun Shi and Chao Tu and Xiaozeng You",

year = "2001",

month = jan,

day = "7",

doi = "10.1016/S0022-2860(00)00728-6",

language = "英语",

volume = "559",

pages = "119--125",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - Crystal and molecular structure of a novel complex [Mn(MOBPT)(H2O)2(NCS)2] (MOBPT = 4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)- 1,2,4-triazole)

AU - Zhu, Dunru

AU - Xu, Yan

AU - Mei, Yuhua

AU - Shi, Yujun

AU - Tu, Chao

AU - You, Xiaozeng

PY - 2001/1/7

Y1 - 2001/1/7

N2 - The molecular structure of a novel manganese(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) has been determined by X-ray analysis, FT-IR and by ESI-MS spectroscopy. The manganese atom is in a distorted octahedral environment. Bidentate chelating ligand (MOBPT) and two cis-oriented thiocyanate anions coordinate to the metal center equatorially and two water molecules coordinate axially. MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. The molecules are stabilized by intermolecular hydrogen bonds in the crystal lattice. Magnetic measurements show that the complex is high-spin species in the 75-300 K range.

AB - The molecular structure of a novel manganese(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) has been determined by X-ray analysis, FT-IR and by ESI-MS spectroscopy. The manganese atom is in a distorted octahedral environment. Bidentate chelating ligand (MOBPT) and two cis-oriented thiocyanate anions coordinate to the metal center equatorially and two water molecules coordinate axially. MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. The molecules are stabilized by intermolecular hydrogen bonds in the crystal lattice. Magnetic measurements show that the complex is high-spin species in the 75-300 K range.

KW - Crystal structure

KW - ESI-MS spectra

KW - FT-IR

KW - Manganese(II) complex

KW - Triazole

UR - http://www.scopus.com/inward/record.url?scp=0035819306&partnerID=8YFLogxK

U2 - 10.1016/S0022-2860(00)00728-6

DO - 10.1016/S0022-2860(00)00728-6

M3 - 文章

AN - SCOPUS:0035819306

SN - 0022-2860

VL - 559

SP - 119

EP - 125

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Crystal and molecular structure of a novel complex [Mn(MOBPT)(H₂O)₂(NCS)₂] (MOBPT = 4-(p-methoxyphenyl)-3,5-bis (pyridin-2-yl)- 1,2,4-triazole)

Abstract

Keywords

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