Crystal structure, magnetic, near-infrared absorption and electrochemical properties of two [Ni(mnt)2]- based compounds

Hong Zhou; Shan Shan Yu; Hai Bao Duan; Xiao Ming Ren

doi:10.3969/j.issn.1001-4861.2013.00.239

Crystal structure, magnetic, near-infrared absorption and electrochemical properties of two [Ni(mnt)₂]^- based compounds

Hong Zhou, Shan Shan Yu, Hai Bao Duan, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Nanjing Xiaozhuang College

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two ion-pair compounds with the formula of (BMIB)[(Ni(mnt)₂]₂ (1) and (BMIO)[(Ni(mnt)₂]₂ (2) (mnt= maleonitrile dithiolate, BMIB=1,4-bis(1-methylimidazolium)butane, BMIO=1,8-bis (1-methylimidazolium)octane) were synthesized and characterized structurally. In 1, the [Ni(mnt)₂]^- form a trimer anions and a mixed column, respectively. The packing structures of 2 are different from 1, the cations and the anions form the irregular alignments. Compound 1 and 2 show remarkable near-IR absorption behavior in the region of 861 and 857 nm respectively. The electrochemical behaviors in the solid state depend on the hydrocarbon chain length in the countercation moiety. Investigations of variable-temperature magnetic susceptibility indicated that 1 shows weak paramagnetic feature from 2 to 400K; the magnetic susceptibility data were fit to the Curie-Weiss equation. 2 is a spin gap system but its magnetic behavior does not follow the Blaney-Bowers spin dimer model. CCDC: 908109, 1; 908110, 2.

Original language	English
Pages (from-to)	1375-1384
Number of pages	10
Journal	Chinese Journal of Inorganic Chemistry
Volume	29
Issue number	7
DOIs	https://doi.org/10.3969/j.issn.1001-4861.2013.00.239
State	Published - Jul 2013

Keywords

Crystal structure
Ion-pair
Magnetic
Near-infrared absorption

Access to Document

10.3969/j.issn.1001-4861.2013.00.239

Cite this

@article{c0d33676176442d595d1e7527868ec12,

title = "Crystal structure, magnetic, near-infrared absorption and electrochemical properties of two [Ni(mnt)2]- based compounds",

abstract = "Two ion-pair compounds with the formula of (BMIB)[(Ni(mnt)2]2 (1) and (BMIO)[(Ni(mnt)2]2 (2) (mnt= maleonitrile dithiolate, BMIB=1,4-bis(1-methylimidazolium)butane, BMIO=1,8-bis (1-methylimidazolium)octane) were synthesized and characterized structurally. In 1, the [Ni(mnt)2]- form a trimer anions and a mixed column, respectively. The packing structures of 2 are different from 1, the cations and the anions form the irregular alignments. Compound 1 and 2 show remarkable near-IR absorption behavior in the region of 861 and 857 nm respectively. The electrochemical behaviors in the solid state depend on the hydrocarbon chain length in the countercation moiety. Investigations of variable-temperature magnetic susceptibility indicated that 1 shows weak paramagnetic feature from 2 to 400K; the magnetic susceptibility data were fit to the Curie-Weiss equation. 2 is a spin gap system but its magnetic behavior does not follow the Blaney-Bowers spin dimer model. CCDC: 908109, 1; 908110, 2.",

keywords = "Crystal structure, Ion-pair, Magnetic, Near-infrared absorption",

author = "Hong Zhou and Yu, {Shan Shan} and Duan, {Hai Bao} and Ren, {Xiao Ming}",

year = "2013",

month = jul,

doi = "10.3969/j.issn.1001-4861.2013.00.239",

language = "英语",

volume = "29",

pages = "1375--1384",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "7",

}

TY - JOUR

T1 - Crystal structure, magnetic, near-infrared absorption and electrochemical properties of two [Ni(mnt)2]- based compounds

AU - Zhou, Hong

AU - Yu, Shan Shan

AU - Duan, Hai Bao

AU - Ren, Xiao Ming

PY - 2013/7

Y1 - 2013/7

N2 - Two ion-pair compounds with the formula of (BMIB)[(Ni(mnt)2]2 (1) and (BMIO)[(Ni(mnt)2]2 (2) (mnt= maleonitrile dithiolate, BMIB=1,4-bis(1-methylimidazolium)butane, BMIO=1,8-bis (1-methylimidazolium)octane) were synthesized and characterized structurally. In 1, the [Ni(mnt)2]- form a trimer anions and a mixed column, respectively. The packing structures of 2 are different from 1, the cations and the anions form the irregular alignments. Compound 1 and 2 show remarkable near-IR absorption behavior in the region of 861 and 857 nm respectively. The electrochemical behaviors in the solid state depend on the hydrocarbon chain length in the countercation moiety. Investigations of variable-temperature magnetic susceptibility indicated that 1 shows weak paramagnetic feature from 2 to 400K; the magnetic susceptibility data were fit to the Curie-Weiss equation. 2 is a spin gap system but its magnetic behavior does not follow the Blaney-Bowers spin dimer model. CCDC: 908109, 1; 908110, 2.

AB - Two ion-pair compounds with the formula of (BMIB)[(Ni(mnt)2]2 (1) and (BMIO)[(Ni(mnt)2]2 (2) (mnt= maleonitrile dithiolate, BMIB=1,4-bis(1-methylimidazolium)butane, BMIO=1,8-bis (1-methylimidazolium)octane) were synthesized and characterized structurally. In 1, the [Ni(mnt)2]- form a trimer anions and a mixed column, respectively. The packing structures of 2 are different from 1, the cations and the anions form the irregular alignments. Compound 1 and 2 show remarkable near-IR absorption behavior in the region of 861 and 857 nm respectively. The electrochemical behaviors in the solid state depend on the hydrocarbon chain length in the countercation moiety. Investigations of variable-temperature magnetic susceptibility indicated that 1 shows weak paramagnetic feature from 2 to 400K; the magnetic susceptibility data were fit to the Curie-Weiss equation. 2 is a spin gap system but its magnetic behavior does not follow the Blaney-Bowers spin dimer model. CCDC: 908109, 1; 908110, 2.

KW - Crystal structure

KW - Ion-pair

KW - Magnetic

KW - Near-infrared absorption

UR - http://www.scopus.com/inward/record.url?scp=84940344003&partnerID=8YFLogxK

U2 - 10.3969/j.issn.1001-4861.2013.00.239

DO - 10.3969/j.issn.1001-4861.2013.00.239

M3 - 文章

AN - SCOPUS:84940344003

SN - 1001-4861

VL - 29

SP - 1375

EP - 1384

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 7

ER -

Crystal structure, magnetic, near-infrared absorption and electrochemical properties of two [Ni(mnt)₂]^- based compounds

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this