Cure kinetic properties of talcum/EPDM composites

Yun Guo Cui; Jun Zhang; Chun Hua Lu; Ya Ru Ni; Zhong Zi Xu

Cure kinetic properties of talcum/EPDM composites

Yun Guo Cui, Jun Zhang, Chun Hua Lu, Ya Ru Ni, Zhong Zi Xu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

Abstract

This work covered the talcum filled with ethylene-propylene-terpolymer (EPDM), and the cure curve was obtained by oscillating disc rheometer under isothermal. By taking first-order-derivative and second-order-derivative of cure conversion respect to time, three characteristic time (t_p, t₁, t₂) was obtained. So the process of vulcanization could be division to four regions. The characteristic of cure time (t_p, t₁, t₂) vs. 1/T is an exponential type dependence, a model of autocatalytic reaction governs the process of vulcanization. With the loading of talcum increasing, the activation energy of the system decreases from 98.7269 kJ/mol to 77.69 kJ/mol.

Original language	English
Pages (from-to)	53-56
Number of pages	4
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	26
Issue number	12
State	Published - Dec 2010

Keywords

Curing
EPDM
Kinetics
Talcum

Cite this

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title = "Cure kinetic properties of talcum/EPDM composites",

abstract = "This work covered the talcum filled with ethylene-propylene-terpolymer (EPDM), and the cure curve was obtained by oscillating disc rheometer under isothermal. By taking first-order-derivative and second-order-derivative of cure conversion respect to time, three characteristic time (tp, t1, t2) was obtained. So the process of vulcanization could be division to four regions. The characteristic of cure time (tp, t1, t2) vs. 1/T is an exponential type dependence, a model of autocatalytic reaction governs the process of vulcanization. With the loading of talcum increasing, the activation energy of the system decreases from 98.7269 kJ/mol to 77.69 kJ/mol.",

keywords = "Curing, EPDM, Kinetics, Talcum",

author = "Cui, {Yun Guo} and Jun Zhang and Lu, {Chun Hua} and Ni, {Ya Ru} and Xu, {Zhong Zi}",

year = "2010",

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volume = "26",

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journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

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T1 - Cure kinetic properties of talcum/EPDM composites

AU - Cui, Yun Guo

AU - Zhang, Jun

AU - Lu, Chun Hua

AU - Ni, Ya Ru

AU - Xu, Zhong Zi

PY - 2010/12

Y1 - 2010/12

N2 - This work covered the talcum filled with ethylene-propylene-terpolymer (EPDM), and the cure curve was obtained by oscillating disc rheometer under isothermal. By taking first-order-derivative and second-order-derivative of cure conversion respect to time, three characteristic time (tp, t1, t2) was obtained. So the process of vulcanization could be division to four regions. The characteristic of cure time (tp, t1, t2) vs. 1/T is an exponential type dependence, a model of autocatalytic reaction governs the process of vulcanization. With the loading of talcum increasing, the activation energy of the system decreases from 98.7269 kJ/mol to 77.69 kJ/mol.

AB - This work covered the talcum filled with ethylene-propylene-terpolymer (EPDM), and the cure curve was obtained by oscillating disc rheometer under isothermal. By taking first-order-derivative and second-order-derivative of cure conversion respect to time, three characteristic time (tp, t1, t2) was obtained. So the process of vulcanization could be division to four regions. The characteristic of cure time (tp, t1, t2) vs. 1/T is an exponential type dependence, a model of autocatalytic reaction governs the process of vulcanization. With the loading of talcum increasing, the activation energy of the system decreases from 98.7269 kJ/mol to 77.69 kJ/mol.

KW - Curing

KW - EPDM

KW - Kinetics

KW - Talcum

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M3 - 文章

AN - SCOPUS:79952470316

SN - 1000-7555

VL - 26

SP - 53

EP - 56

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 12

ER -

Cure kinetic properties of talcum/EPDM composites

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