Denitrative Mizoroki-Heck reaction of unactivated alkenes

Fei Zhang; Fei Wang; Yao Zhao; Rizhi Chen; Xiaojin Wu

doi:10.1039/d3qo00132f

Denitrative Mizoroki-Heck reaction of unactivated alkenes

Fei Zhang, Fei Wang, Yao Zhao, Rizhi Chen, Xiaojin Wu

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A general palladium-catalyzed denitrative Mizoroki-Heck reaction of unactivated alkenes was developed. Most topical classes of nitroarenes efficiently react with various unactivated alkenes with high E/Z selectivity. A gram-scale reaction, chemoselective dual Heck transformation and modification of complex molecules have further demonstrated that the denitrative reaction of unactivated alkenes is a powerful complementary strategy to the classical Mizoroki-Heck reaction.

Original language	English
Pages (from-to)	2193-2197
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	10
Issue number	9
DOIs	https://doi.org/10.1039/d3qo00132f
State	Published - 25 Mar 2023

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abstract = "A general palladium-catalyzed denitrative Mizoroki-Heck reaction of unactivated alkenes was developed. Most topical classes of nitroarenes efficiently react with various unactivated alkenes with high E/Z selectivity. A gram-scale reaction, chemoselective dual Heck transformation and modification of complex molecules have further demonstrated that the denitrative reaction of unactivated alkenes is a powerful complementary strategy to the classical Mizoroki-Heck reaction.",

author = "Fei Zhang and Fei Wang and Yao Zhao and Rizhi Chen and Xiaojin Wu",

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AU - Zhang, Fei

AU - Wang, Fei

AU - Zhao, Yao

AU - Chen, Rizhi

AU - Wu, Xiaojin

PY - 2023/3/25

Y1 - 2023/3/25

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AB - A general palladium-catalyzed denitrative Mizoroki-Heck reaction of unactivated alkenes was developed. Most topical classes of nitroarenes efficiently react with various unactivated alkenes with high E/Z selectivity. A gram-scale reaction, chemoselective dual Heck transformation and modification of complex molecules have further demonstrated that the denitrative reaction of unactivated alkenes is a powerful complementary strategy to the classical Mizoroki-Heck reaction.

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DO - 10.1039/d3qo00132f

M3 - 文章

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JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

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ER -

Denitrative Mizoroki-Heck reaction of unactivated alkenes

Abstract

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