Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Jian Xiao; Teck Peng Loh

doi:10.1055/s-2007-970774

Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Jian Xiao, Teck Peng Loh

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.

Original language	English
Pages (from-to)	815-817
Number of pages	3
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.1055/s-2007-970774
State	Published - 16 Mar 2007
Externally published	Yes

Keywords

Allyltributylstannane
Chiral indium complex
One-pot three-component Mannich-type reaction

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10.1055/s-2007-970774

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title = "Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water",

abstract = "A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.",

keywords = "Allyltributylstannane, Chiral indium complex, One-pot three-component Mannich-type reaction",

author = "Jian Xiao and Loh, {Teck Peng}",

year = "2007",

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doi = "10.1055/s-2007-970774",

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journal = "Synlett",

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T2 - Application to one-pot three-component Mannich-type reactions in water

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AU - Loh, Teck Peng

PY - 2007/3/16

Y1 - 2007/3/16

N2 - A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.

AB - A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.

KW - Allyltributylstannane

KW - Chiral indium complex

KW - One-pot three-component Mannich-type reaction

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DO - 10.1055/s-2007-970774

M3 - 文章

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JO - Synlett

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ER -

Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Abstract

Keywords

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