Detection of NADH and ethanol at titanium containing MCM-41 with low overpotential

Zhihui Dai; Guofei Lu; Jianchun Bao; Xiaohua Huang; Huangxian Ju

doi:10.1002/elan.200703888

Detection of NADH and ethanol at titanium containing MCM-41 with low overpotential

Zhihui Dai, Guofei Lu, Jianchun Bao, Xiaohua Huang, Huangxian Ju

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Titanium-containing MCM-41 (Ti-MCM-41) modified glassy carbon electrode (GCE) can exhibit an excellent electrocatalytic activity towards the oxidation of β-Nicotinamide adenine dinucleotide (NADH). A dramatic decrease in the overvoltage of NADH oxidation reaction is observed at 0.28 V vs. SCE. The application in the amperometric biosensing of ethanol using alcohol dehydrogenase enzyme (ADH) also has been demonstrated with this material. The proposed sensor shows a highly sensitivity, an acceptable reproducibility and a good stability. The linear range of ethanol is 25-1000 μM and the detection limit is 8.0 μM. Ti-MCM-41 modified electrode not only can be used to detect the concentration of NADH in biochemical reaction, but also as the potential matrix for the construction of dehydrogenases sensor.

Original language	English
Pages (from-to)	1591-1596
Number of pages	6
Journal	Electroanalysis
Volume	19
Issue number	15
DOIs	https://doi.org/10.1002/elan.200703888
State	Published - Aug 2007
Externally published	Yes

Keywords

ADH
Electrocatalytic
Ethanol
NADH
Sensors
Ti-MCM-41

Access to Document

10.1002/elan.200703888

Cite this

@article{263f8caa02b4412aa0cba7e45aa20d76,

title = "Detection of NADH and ethanol at titanium containing MCM-41 with low overpotential",

abstract = "Titanium-containing MCM-41 (Ti-MCM-41) modified glassy carbon electrode (GCE) can exhibit an excellent electrocatalytic activity towards the oxidation of β-Nicotinamide adenine dinucleotide (NADH). A dramatic decrease in the overvoltage of NADH oxidation reaction is observed at 0.28 V vs. SCE. The application in the amperometric biosensing of ethanol using alcohol dehydrogenase enzyme (ADH) also has been demonstrated with this material. The proposed sensor shows a highly sensitivity, an acceptable reproducibility and a good stability. The linear range of ethanol is 25-1000 μM and the detection limit is 8.0 μM. Ti-MCM-41 modified electrode not only can be used to detect the concentration of NADH in biochemical reaction, but also as the potential matrix for the construction of dehydrogenases sensor.",

keywords = "ADH, Electrocatalytic, Ethanol, NADH, Sensors, Ti-MCM-41",

author = "Zhihui Dai and Guofei Lu and Jianchun Bao and Xiaohua Huang and Huangxian Ju",

year = "2007",

month = aug,

doi = "10.1002/elan.200703888",

language = "英语",

volume = "19",

pages = "1591--1596",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-VCH Verlag",

number = "15",

}

TY - JOUR

T1 - Detection of NADH and ethanol at titanium containing MCM-41 with low overpotential

AU - Dai, Zhihui

AU - Lu, Guofei

AU - Bao, Jianchun

AU - Huang, Xiaohua

AU - Ju, Huangxian

PY - 2007/8

Y1 - 2007/8

N2 - Titanium-containing MCM-41 (Ti-MCM-41) modified glassy carbon electrode (GCE) can exhibit an excellent electrocatalytic activity towards the oxidation of β-Nicotinamide adenine dinucleotide (NADH). A dramatic decrease in the overvoltage of NADH oxidation reaction is observed at 0.28 V vs. SCE. The application in the amperometric biosensing of ethanol using alcohol dehydrogenase enzyme (ADH) also has been demonstrated with this material. The proposed sensor shows a highly sensitivity, an acceptable reproducibility and a good stability. The linear range of ethanol is 25-1000 μM and the detection limit is 8.0 μM. Ti-MCM-41 modified electrode not only can be used to detect the concentration of NADH in biochemical reaction, but also as the potential matrix for the construction of dehydrogenases sensor.

AB - Titanium-containing MCM-41 (Ti-MCM-41) modified glassy carbon electrode (GCE) can exhibit an excellent electrocatalytic activity towards the oxidation of β-Nicotinamide adenine dinucleotide (NADH). A dramatic decrease in the overvoltage of NADH oxidation reaction is observed at 0.28 V vs. SCE. The application in the amperometric biosensing of ethanol using alcohol dehydrogenase enzyme (ADH) also has been demonstrated with this material. The proposed sensor shows a highly sensitivity, an acceptable reproducibility and a good stability. The linear range of ethanol is 25-1000 μM and the detection limit is 8.0 μM. Ti-MCM-41 modified electrode not only can be used to detect the concentration of NADH in biochemical reaction, but also as the potential matrix for the construction of dehydrogenases sensor.

KW - ADH

KW - Electrocatalytic

KW - Ethanol

KW - NADH

KW - Sensors

KW - Ti-MCM-41

UR - http://www.scopus.com/inward/record.url?scp=34547809951&partnerID=8YFLogxK

U2 - 10.1002/elan.200703888

DO - 10.1002/elan.200703888

M3 - 文章

AN - SCOPUS:34547809951

SN - 1040-0397

VL - 19

SP - 1591

EP - 1596

JO - Electroanalysis

JF - Electroanalysis

IS - 15

ER -

Detection of NADH and ethanol at titanium containing MCM-41 with low overpotential

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this