Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block

Magnus R. Buchner; Sudip Pan; Christina Poggel; Nils Spang; Matthias Müller; Gernot Frenking; Jörg Sundermeyer

doi:10.1021/acs.organomet.0c00434

Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block

Magnus R. Buchner, Sudip Pan, Christina Poggel, Nils Spang, Matthias Müller, Gernot Frenking, Jörg Sundermeyer

University of Marburg

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks. However, no s-block metal complexes with a double bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be═C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and computational means.

Original language	English
Pages (from-to)	3224-3231
Number of pages	8
Journal	Organometallics
Volume	39
Issue number	17
DOIs	https://doi.org/10.1021/acs.organomet.0c00434
State	Published - 14 Sep 2020
Externally published	Yes

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abstract = "Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks. However, no s-block metal complexes with a double bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be═C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and computational means.",

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AU - Poggel, Christina

AU - Spang, Nils

AU - Müller, Matthias

AU - Frenking, Gernot

AU - Sundermeyer, Jörg

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Y1 - 2020/9/14

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AB - Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks. However, no s-block metal complexes with a double bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be═C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and computational means.

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Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block

Abstract

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