Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

Zhi Liang Shen; Kelvin Kau Kiat Goh; Colin Hong An Wong; Yong Sheng Yang; Yin Chang Lai; Hao Lun Cheong; Teck Peng Loh

doi:10.1039/c0cc05597b

Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

Zhi Liang Shen, Kelvin Kau Kiat Goh, Colin Hong An Wong, Yong Sheng Yang, Yin Chang Lai, Hao Lun Cheong, Teck Peng Loh

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.

Original language	English
Pages (from-to)	4778-4780
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	16
DOIs	https://doi.org/10.1039/c0cc05597b
State	Published - 4 Apr 2011
Externally published	Yes

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title = "Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide",

abstract = "An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.",

author = "Shen, {Zhi Liang} and Goh, {Kelvin Kau Kiat} and Wong, {Colin Hong An} and Yang, {Yong Sheng} and Lai, {Yin Chang} and Cheong, {Hao Lun} and Loh, {Teck Peng}",

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doi = "10.1039/c0cc05597b",

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volume = "47",

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T1 - Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

AU - Shen, Zhi Liang

AU - Goh, Kelvin Kau Kiat

AU - Wong, Colin Hong An

AU - Yang, Yong Sheng

AU - Lai, Yin Chang

AU - Cheong, Hao Lun

AU - Loh, Teck Peng

PY - 2011/4/4

Y1 - 2011/4/4

N2 - An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.

AB - An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.

UR - http://www.scopus.com/inward/record.url?scp=79953689598&partnerID=8YFLogxK

U2 - 10.1039/c0cc05597b

DO - 10.1039/c0cc05597b

M3 - 文章

C2 - 21412540

AN - SCOPUS:79953689598

SN - 1359-7345

VL - 47

SP - 4778

EP - 4780

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide

Abstract

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