TY - JOUR
T1 - Effect of stabilizer EDTA on the thermal hazard of green synthesis process of adipic acid and development of microchannel continuous flow process
AU - He, Weidong
AU - Li, Yuanyuan
AU - Ni, Lei
AU - Zhu, Wen
N1 - Publisher Copyright:
© 2023 by the author(s).
PY - 2023
Y1 - 2023
N2 - In the green synthesis reaction of adipic acid, the oxidant H2O2 undergoes exothermic decomposition easily and the high exothermic amount of the reaction can easily lead to thermal runaway. This study carries out calorimetric experiments on the green synthesis reaction of adipic acid, studies the effect of the stabilizer ethylenediaminetetraacetic acid (EDTA) on the safety of the synthesis reaction, and further explores the effect of EDTA on the Na2WO4-catalyzed decomposition reaction of H2O2 under the conditions of continuous flow, and develops the microchannel continuous flow process of green synthesis of adipic acid containing EDTA, in order to provide theoretical support for the improvement of intrinsic safety of green synthesis of adipic acid.
AB - In the green synthesis reaction of adipic acid, the oxidant H2O2 undergoes exothermic decomposition easily and the high exothermic amount of the reaction can easily lead to thermal runaway. This study carries out calorimetric experiments on the green synthesis reaction of adipic acid, studies the effect of the stabilizer ethylenediaminetetraacetic acid (EDTA) on the safety of the synthesis reaction, and further explores the effect of EDTA on the Na2WO4-catalyzed decomposition reaction of H2O2 under the conditions of continuous flow, and develops the microchannel continuous flow process of green synthesis of adipic acid containing EDTA, in order to provide theoretical support for the improvement of intrinsic safety of green synthesis of adipic acid.
UR - http://www.scopus.com/inward/record.url?scp=85192550488&partnerID=8YFLogxK
U2 - 10.48130/EMST-2023-0022
DO - 10.48130/EMST-2023-0022
M3 - 文章
AN - SCOPUS:85192550488
SN - 2832-448X
VL - 3
JO - Emergency Management Science and Technology
JF - Emergency Management Science and Technology
M1 - 22
ER -