Effects of sodium bromide and sodium iodide on the thermal decomposition characteristics of nitrification wastes

Heng Zao Yang; Juan Zhai; Jun Cheng Jiang; An Chi Huang

doi:10.1007/s10973-024-13826-w

Effects of sodium bromide and sodium iodide on the thermal decomposition characteristics of nitrification wastes

Heng Zao Yang, Juan Zhai, Jun Cheng Jiang, An Chi Huang

College of Safety Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The handling of nitrification waste (NW) presents considerable safety risks due to its propensity for thermal runaway. This study investigates the influence of sodium bromide (NaBr) and sodium iodide (NaI) on the thermal breakdown properties of NW. The thermal stability and apparent activation energy (E_a) were examined using differential scanning calorimetry and thermogravimetric analyzer. The results demonstrate that the inclusion of NaBr and NaI modifies the thermal breakdown characteristics of NW. NaBr effectively decreases the E_a from 246.6 to 78.6 kJ mol⁻¹ and enhances the onset temperature (T_o) from 141.0 to 107.7 °C during the initial decomposition stage. However, NaI reduces the E_a to 154.49 kJ mol⁻¹ while having a negligible effect on the T_o. The findings indicate that the thermal behavior of NW can be altered by NaBr and NaI, providing valuable information for the development of safer handling and treatment methods. This study offers useful data for the advancement of enhanced safety standards in the management of NW.

Original language	English
Journal	Journal of Thermal Analysis and Calorimetry
DOIs	https://doi.org/10.1007/s10973-024-13826-w
State	Accepted/In press - 2024

Keywords

Apparent activation energy
Differential scanning calorimetry
Thermal behavior
Thermal stability
Thermogravimetric analyzer

Access to Document

10.1007/s10973-024-13826-w

Cite this

@article{a60a6c52b1e54c17a2d35cd32b50932c,

title = "Effects of sodium bromide and sodium iodide on the thermal decomposition characteristics of nitrification wastes",

abstract = "The handling of nitrification waste (NW) presents considerable safety risks due to its propensity for thermal runaway. This study investigates the influence of sodium bromide (NaBr) and sodium iodide (NaI) on the thermal breakdown properties of NW. The thermal stability and apparent activation energy (Ea) were examined using differential scanning calorimetry and thermogravimetric analyzer. The results demonstrate that the inclusion of NaBr and NaI modifies the thermal breakdown characteristics of NW. NaBr effectively decreases the Ea from 246.6 to 78.6 kJ mol−1 and enhances the onset temperature (To) from 141.0 to 107.7 °C during the initial decomposition stage. However, NaI reduces the Ea to 154.49 kJ mol−1 while having a negligible effect on the To. The findings indicate that the thermal behavior of NW can be altered by NaBr and NaI, providing valuable information for the development of safer handling and treatment methods. This study offers useful data for the advancement of enhanced safety standards in the management of NW.",

keywords = "Apparent activation energy, Differential scanning calorimetry, Thermal behavior, Thermal stability, Thermogravimetric analyzer",

author = "Yang, {Heng Zao} and Juan Zhai and Jiang, {Jun Cheng} and Huang, {An Chi}",

note = "Publisher Copyright: {\textcopyright} Akad{\'e}miai Kiad{\'o}, Budapest, Hungary 2024.",

year = "2024",

doi = "10.1007/s10973-024-13826-w",

language = "英语",

journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Science and Business Media B.V.",

}

TY - JOUR

T1 - Effects of sodium bromide and sodium iodide on the thermal decomposition characteristics of nitrification wastes

AU - Yang, Heng Zao

AU - Zhai, Juan

AU - Jiang, Jun Cheng

AU - Huang, An Chi

N1 - Publisher Copyright: © Akadémiai Kiadó, Budapest, Hungary 2024.

PY - 2024

Y1 - 2024

N2 - The handling of nitrification waste (NW) presents considerable safety risks due to its propensity for thermal runaway. This study investigates the influence of sodium bromide (NaBr) and sodium iodide (NaI) on the thermal breakdown properties of NW. The thermal stability and apparent activation energy (Ea) were examined using differential scanning calorimetry and thermogravimetric analyzer. The results demonstrate that the inclusion of NaBr and NaI modifies the thermal breakdown characteristics of NW. NaBr effectively decreases the Ea from 246.6 to 78.6 kJ mol−1 and enhances the onset temperature (To) from 141.0 to 107.7 °C during the initial decomposition stage. However, NaI reduces the Ea to 154.49 kJ mol−1 while having a negligible effect on the To. The findings indicate that the thermal behavior of NW can be altered by NaBr and NaI, providing valuable information for the development of safer handling and treatment methods. This study offers useful data for the advancement of enhanced safety standards in the management of NW.

AB - The handling of nitrification waste (NW) presents considerable safety risks due to its propensity for thermal runaway. This study investigates the influence of sodium bromide (NaBr) and sodium iodide (NaI) on the thermal breakdown properties of NW. The thermal stability and apparent activation energy (Ea) were examined using differential scanning calorimetry and thermogravimetric analyzer. The results demonstrate that the inclusion of NaBr and NaI modifies the thermal breakdown characteristics of NW. NaBr effectively decreases the Ea from 246.6 to 78.6 kJ mol−1 and enhances the onset temperature (To) from 141.0 to 107.7 °C during the initial decomposition stage. However, NaI reduces the Ea to 154.49 kJ mol−1 while having a negligible effect on the To. The findings indicate that the thermal behavior of NW can be altered by NaBr and NaI, providing valuable information for the development of safer handling and treatment methods. This study offers useful data for the advancement of enhanced safety standards in the management of NW.

KW - Apparent activation energy

KW - Differential scanning calorimetry

KW - Thermal behavior

KW - Thermal stability

KW - Thermogravimetric analyzer

UR - http://www.scopus.com/inward/record.url?scp=85208549597&partnerID=8YFLogxK

U2 - 10.1007/s10973-024-13826-w

DO - 10.1007/s10973-024-13826-w

M3 - 文章

AN - SCOPUS:85208549597

SN - 1388-6150

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

ER -

Effects of sodium bromide and sodium iodide on the thermal decomposition characteristics of nitrification wastes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this