Efficient CO2/N2 separation by mixed matrix membrane with amide functionalized porous coordination polymer filler

Qianqian Li; Jingui Duan; Wanqin Jin

doi:10.1016/j.cclet.2017.11.008

Efficient CO₂/N₂ separation by mixed matrix membrane with amide functionalized porous coordination polymer filler

Qianqian Li, Jingui Duan, Wanqin Jin

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Mixed matrix membrane used to selective removal of CO₂ was considered as an efficient solution to energy and environmental sustainability. In this study, a MMM that consists of amide functionalized porous coordination polymer filler (MIL-53-NH₂) was successfully prepared, which sharply promotes the CO₂/N₂ selectivity from 44 (neat polymeric membrane) to 75. Remarkably, the positive effect of amide group and nanochannel of MIL-53-NH₂ filler was illustrated by decreased selectivity of the MMM with formic acid modified MIL-53-NH₂ filler (MIL-53-NHCOH).

Original language	English
Pages (from-to)	854-856
Number of pages	3
Journal	Chinese Chemical Letters
Volume	29
Issue number	6
DOIs	https://doi.org/10.1016/j.cclet.2017.11.008
State	Published - Jun 2018

Keywords

Amide group
CO/N separation
Mixed matrix membrane
Porous coordination polymer

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10.1016/j.cclet.2017.11.008

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title = "Efficient CO2/N2 separation by mixed matrix membrane with amide functionalized porous coordination polymer filler",

abstract = "Mixed matrix membrane used to selective removal of CO2 was considered as an efficient solution to energy and environmental sustainability. In this study, a MMM that consists of amide functionalized porous coordination polymer filler (MIL-53-NH2) was successfully prepared, which sharply promotes the CO2/N2 selectivity from 44 (neat polymeric membrane) to 75. Remarkably, the positive effect of amide group and nanochannel of MIL-53-NH2 filler was illustrated by decreased selectivity of the MMM with formic acid modified MIL-53-NH2 filler (MIL-53-NHCOH).",

keywords = "Amide group, CO/N separation, Mixed matrix membrane, Porous coordination polymer",

author = "Qianqian Li and Jingui Duan and Wanqin Jin",

note = "Publisher Copyright: {\textcopyright} 2018 The Author",

year = "2018",

month = jun,

doi = "10.1016/j.cclet.2017.11.008",

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T1 - Efficient CO2/N2 separation by mixed matrix membrane with amide functionalized porous coordination polymer filler

AU - Li, Qianqian

AU - Duan, Jingui

AU - Jin, Wanqin

PY - 2018/6

Y1 - 2018/6

N2 - Mixed matrix membrane used to selective removal of CO2 was considered as an efficient solution to energy and environmental sustainability. In this study, a MMM that consists of amide functionalized porous coordination polymer filler (MIL-53-NH2) was successfully prepared, which sharply promotes the CO2/N2 selectivity from 44 (neat polymeric membrane) to 75. Remarkably, the positive effect of amide group and nanochannel of MIL-53-NH2 filler was illustrated by decreased selectivity of the MMM with formic acid modified MIL-53-NH2 filler (MIL-53-NHCOH).

AB - Mixed matrix membrane used to selective removal of CO2 was considered as an efficient solution to energy and environmental sustainability. In this study, a MMM that consists of amide functionalized porous coordination polymer filler (MIL-53-NH2) was successfully prepared, which sharply promotes the CO2/N2 selectivity from 44 (neat polymeric membrane) to 75. Remarkably, the positive effect of amide group and nanochannel of MIL-53-NH2 filler was illustrated by decreased selectivity of the MMM with formic acid modified MIL-53-NH2 filler (MIL-53-NHCOH).

KW - Amide group

KW - CO/N separation

KW - Mixed matrix membrane

KW - Porous coordination polymer

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DO - 10.1016/j.cclet.2017.11.008

M3 - 文章

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SN - 1001-8417

VL - 29

SP - 854

EP - 856

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 6

ER -

Efficient CO₂/N₂ separation by mixed matrix membrane with amide functionalized porous coordination polymer filler

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Keywords

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