Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO3H

Feng Zhou; Jihai Tang; Zhaoyang Fei; Xiaoli Zhou; Xian Chen; Mifen Cui; Xu Qiao

doi:10.1007/s10934-013-9759-2

Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO₃H

Feng Zhou, Jihai Tang, Zhaoyang Fei, Xiaoli Zhou, Xian Chen, Mifen Cui, Xu Qiao

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A set of propysulfonic acid modified mesostructured silica materials (SBA-15-SO₃H) were prepared by a convenient one-pot co-condensation method. Samples were characterized by XRD, FT-IR, Py-FTIR, N₂ adsorption-desorption, elemental analysis and acid-base titration. The catalysts exhibited excellent activities and selectivities for addition esterification of acrylic acid and cyclohexene. The highest catalytic activity (82.8 %) and selectivity (92.6 %) were obtained over SBA-15-SO₃H (15 %). The efficient catalytic performance of SBA-15-SO₃H (15 %) was attributed to the high surface area, proper mesopore texture and presence of sulfonic acid groups in its structure. SBA-15-SO₃H catalyst was easily separated and recycled with high stability.

Original language	English
Pages (from-to)	149-155
Number of pages	7
Journal	Journal of Porous Materials
Volume	21
Issue number	2
DOIs	https://doi.org/10.1007/s10934-013-9759-2
State	Published - Apr 2014

Keywords

Addition esterification
Cyclohexyl acrylate
Solid acid catalyst

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10.1007/s10934-013-9759-2

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title = "Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO3H",

abstract = "A set of propysulfonic acid modified mesostructured silica materials (SBA-15-SO3H) were prepared by a convenient one-pot co-condensation method. Samples were characterized by XRD, FT-IR, Py-FTIR, N2 adsorption-desorption, elemental analysis and acid-base titration. The catalysts exhibited excellent activities and selectivities for addition esterification of acrylic acid and cyclohexene. The highest catalytic activity (82.8 %) and selectivity (92.6 %) were obtained over SBA-15-SO3H (15 %). The efficient catalytic performance of SBA-15-SO3H (15 %) was attributed to the high surface area, proper mesopore texture and presence of sulfonic acid groups in its structure. SBA-15-SO3H catalyst was easily separated and recycled with high stability.",

keywords = "Addition esterification, Cyclohexyl acrylate, Solid acid catalyst",

author = "Feng Zhou and Jihai Tang and Zhaoyang Fei and Xiaoli Zhou and Xian Chen and Mifen Cui and Xu Qiao",

year = "2014",

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T1 - Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO3H

AU - Zhou, Feng

AU - Tang, Jihai

AU - Fei, Zhaoyang

AU - Zhou, Xiaoli

AU - Chen, Xian

AU - Cui, Mifen

AU - Qiao, Xu

PY - 2014/4

Y1 - 2014/4

N2 - A set of propysulfonic acid modified mesostructured silica materials (SBA-15-SO3H) were prepared by a convenient one-pot co-condensation method. Samples were characterized by XRD, FT-IR, Py-FTIR, N2 adsorption-desorption, elemental analysis and acid-base titration. The catalysts exhibited excellent activities and selectivities for addition esterification of acrylic acid and cyclohexene. The highest catalytic activity (82.8 %) and selectivity (92.6 %) were obtained over SBA-15-SO3H (15 %). The efficient catalytic performance of SBA-15-SO3H (15 %) was attributed to the high surface area, proper mesopore texture and presence of sulfonic acid groups in its structure. SBA-15-SO3H catalyst was easily separated and recycled with high stability.

AB - A set of propysulfonic acid modified mesostructured silica materials (SBA-15-SO3H) were prepared by a convenient one-pot co-condensation method. Samples were characterized by XRD, FT-IR, Py-FTIR, N2 adsorption-desorption, elemental analysis and acid-base titration. The catalysts exhibited excellent activities and selectivities for addition esterification of acrylic acid and cyclohexene. The highest catalytic activity (82.8 %) and selectivity (92.6 %) were obtained over SBA-15-SO3H (15 %). The efficient catalytic performance of SBA-15-SO3H (15 %) was attributed to the high surface area, proper mesopore texture and presence of sulfonic acid groups in its structure. SBA-15-SO3H catalyst was easily separated and recycled with high stability.

KW - Addition esterification

KW - Cyclohexyl acrylate

KW - Solid acid catalyst

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DO - 10.1007/s10934-013-9759-2

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SN - 1380-2224

VL - 21

SP - 149

EP - 155

JO - Journal of Porous Materials

JF - Journal of Porous Materials

IS - 2

ER -

Efficient cyclohexyl acrylate production by direct addition of acrylic acid and cyclohexene over SBA-15-SO₃H

Abstract

Keywords

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