Electrochemical intercalation of lithium ions into LiV3O8 in an aqueous electrolyte

G. J. Wang; Q. T. Qu; B. Wang; Y. Shi; S. Tian; Y. P. Wu; R. Holze

doi:10.1016/j.jpowsour.2008.11.006

Electrochemical intercalation of lithium ions into LiV₃O₈ in an aqueous electrolyte

G. J. Wang, Q. T. Qu, B. Wang, Y. Shi, S. Tian, Y. P. Wu, R. Holze

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Electrochemical intercalation of lithium ions from a saturated LiNO₃ aqueous electrolyte solution into LiV₃O₈ prepared by a solid-state reaction at 680 °C was studied with cyclic voltammetry and electrochemical impedance spectroscopy (EIS). Results show that there are three steps of intercalation in the presence of an aqueous electrolyte, in agreement with those previously observed with organic liquid electrolytes. In addition, variations of several parameters including the charge transfer resistance (R_ct), the capacitance of the double layer (C_DL), the Warburg diffusion impedance (Z_w), and diffusion coefficient of lithium ions (D_{L i+}) during the intercalation process are reported.

Original language	English
Pages (from-to)	503-506
Number of pages	4
Journal	Journal of Power Sources
Volume	189
Issue number	1
DOIs	https://doi.org/10.1016/j.jpowsour.2008.11.006
State	Published - 1 Apr 2009
Externally published	Yes

Keywords

Aqueous electrolyte
Aqueous rechargeable lithium battery (ARLB)
Cyclic voltammogram
LiVO

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2008.11.006

Cite this

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title = "Electrochemical intercalation of lithium ions into LiV3O8 in an aqueous electrolyte",

abstract = "Electrochemical intercalation of lithium ions from a saturated LiNO3 aqueous electrolyte solution into LiV3O8 prepared by a solid-state reaction at 680 °C was studied with cyclic voltammetry and electrochemical impedance spectroscopy (EIS). Results show that there are three steps of intercalation in the presence of an aqueous electrolyte, in agreement with those previously observed with organic liquid electrolytes. In addition, variations of several parameters including the charge transfer resistance (Rct), the capacitance of the double layer (CDL), the Warburg diffusion impedance (Zw), and diffusion coefficient of lithium ions (DL i+) during the intercalation process are reported.",

keywords = "Aqueous electrolyte, Aqueous rechargeable lithium battery (ARLB), Cyclic voltammogram, LiVO",

author = "Wang, {G. J.} and Qu, {Q. T.} and B. Wang and Y. Shi and S. Tian and Wu, {Y. P.} and R. Holze",

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T1 - Electrochemical intercalation of lithium ions into LiV3O8 in an aqueous electrolyte

AU - Wang, G. J.

AU - Qu, Q. T.

AU - Wang, B.

AU - Shi, Y.

AU - Tian, S.

AU - Wu, Y. P.

AU - Holze, R.

PY - 2009/4/1

Y1 - 2009/4/1

N2 - Electrochemical intercalation of lithium ions from a saturated LiNO3 aqueous electrolyte solution into LiV3O8 prepared by a solid-state reaction at 680 °C was studied with cyclic voltammetry and electrochemical impedance spectroscopy (EIS). Results show that there are three steps of intercalation in the presence of an aqueous electrolyte, in agreement with those previously observed with organic liquid electrolytes. In addition, variations of several parameters including the charge transfer resistance (Rct), the capacitance of the double layer (CDL), the Warburg diffusion impedance (Zw), and diffusion coefficient of lithium ions (DL i+) during the intercalation process are reported.

AB - Electrochemical intercalation of lithium ions from a saturated LiNO3 aqueous electrolyte solution into LiV3O8 prepared by a solid-state reaction at 680 °C was studied with cyclic voltammetry and electrochemical impedance spectroscopy (EIS). Results show that there are three steps of intercalation in the presence of an aqueous electrolyte, in agreement with those previously observed with organic liquid electrolytes. In addition, variations of several parameters including the charge transfer resistance (Rct), the capacitance of the double layer (CDL), the Warburg diffusion impedance (Zw), and diffusion coefficient of lithium ions (DL i+) during the intercalation process are reported.

KW - Aqueous electrolyte

KW - Aqueous rechargeable lithium battery (ARLB)

KW - Cyclic voltammogram

KW - LiVO

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DO - 10.1016/j.jpowsour.2008.11.006

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