Electrochemical properties of LiFe1-2xMnxMgxPO4/C cathode material as lithium ion batteries

Cai Rong Kang, Xiang Yin Mo, Yi Ding, Chun Hua Lu, Zhong Zi Xu, Jian Shen

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

LiFe0.8Mn0.1Mg0.1PO4/C and LiFePO4/C were respectively prepared using MnCO3 and (MgCO3)4 ·Mg(OH)2·5H2O, glucose as doping starting materials by high-temperature solid state reaction under Ar atmosphere. The prepared composites were characterized by X-ray diffraction, scanning electron microscope and FT-IR spectroscopic, and electrochemical performance was investigated with constant current charge-discharge experiment. The results showed that LiFe0.8Mn0.1Mg0.1PO4/C preserved olivine structure with no impurity. Compared with LiFePO4/C, the electronic conductivity of LiFe0.8Mn0.1Mg0.1PO4/C has been improved. LiFe0.8Mn0.1Mg0.1PO4/C had a reversible capacity of 131mAh/g at 0.1C discharge rate, and showed good electrochemical properties.

Original languageEnglish
Pages (from-to)208-210
Number of pages3
JournalGongneng Cailiao/Journal of Functional Materials
Volume41
Issue number2
StatePublished - Feb 2010

Keywords

  • Cathode material
  • Doping-ion
  • LiFePO
  • Lithium-ion battery

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