Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

Wenzhong Yang; Hui Cang; Yongming Tang; Jintang Wang; Yuanxiang Shi

doi:10.1007/s10800-007-9470-6

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

Wenzhong Yang, Hui Cang, Yongming Tang, Jintang Wang, Yuanxiang Shi

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF₄ ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

Original language	English
Pages (from-to)	537-542
Number of pages	6
Journal	Journal of Applied Electrochemistry
Volume	38
Issue number	4
DOIs	https://doi.org/10.1007/s10800-007-9470-6
State	Published - Apr 2008

Keywords

Antimony
Electrodeposition
Ionic liquid
Tetrafluoroborate
Tin

Access to Document

10.1007/s10800-007-9470-6

Cite this

@article{60f861ec0a5f4225906bfe030a2caad0,

title = "Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid",

abstract = "The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.",

keywords = "Antimony, Electrodeposition, Ionic liquid, Tetrafluoroborate, Tin",

author = "Wenzhong Yang and Hui Cang and Yongming Tang and Jintang Wang and Yuanxiang Shi",

year = "2008",

month = apr,

doi = "10.1007/s10800-007-9470-6",

language = "英语",

volume = "38",

pages = "537--542",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

publisher = "Springer Netherlands",

number = "4",

}

TY - JOUR

T1 - Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

AU - Yang, Wenzhong

AU - Cang, Hui

AU - Tang, Yongming

AU - Wang, Jintang

AU - Shi, Yuanxiang

PY - 2008/4

Y1 - 2008/4

N2 - The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

AB - The electrodepositions of Sn(II) and Sb(III) were studied in the [EMIm]BF4 ionic liquid at ambient temperature. Linear sweep voltammetry (LSV) results indicated that the reductions of Sn(II) and Sb(III) on Pt electrode are electrochemically irreversible. The diffusion coefficients of Sn(II) and Sb(III) in the ionic liquid electrolyte were determined in terms of the LSV data. Tin and antimony ions form simpler Sn(II) chlorocomplex species and higher Sb(III) chlorocomplexes, respectively present in the ionic liquid electrolyte. Energy dispersive X-ray spectroscopy (EDX) analysis revealed that tin and antimony alloys can be electroplated in the ionic liquid electrolyte.

KW - Antimony

KW - Electrodeposition

KW - Ionic liquid

KW - Tetrafluoroborate

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=40849118210&partnerID=8YFLogxK

U2 - 10.1007/s10800-007-9470-6

DO - 10.1007/s10800-007-9470-6

M3 - 文章

AN - SCOPUS:40849118210

SN - 0021-891X

VL - 38

SP - 537

EP - 542

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 4

ER -

Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this