Electrospun porous NiCo2O4 nanotubes as advanced electrodes for electrochemical capacitors

Linlin Li, Shengjie Peng, Yanling Cheah, Peifen Teh, Jin Wang, Grace Wee, Yahwen Ko, Chuiling Wong, Madhavi Srinivasan

Research output: Contribution to journalArticlepeer-review

266 Scopus citations

Abstract

Novel, porous NiCo2O4 nanotubes (NCO-NTs) are prepared by a single-spinneret electrospinning technique followed by calcination in air. The obtained NCO-NTs display a one-dimensional architecture with a porous structure and hollow interiors. The effect of precursor concentration on the morphologies of the products is investigated. Due to their unique structure, the prepared NCO-NT electrode exhibits a high specific capacitance (1647 F g-1 at 1 A g-1), excellent rate capability (77.3 % capacity retention at 25 A g-1), and outstanding cycling stability (6.4 % loss after 3000 cycles), which indicates it has great potential for high-performance electrochemical capacitors. The desirable enhanced capacitive performance of NCO-NTs can be attributed to the relatively large specific surface area of these porous and hollow one-dimensional nanostructures.

Original languageEnglish
Pages (from-to)5892-5898
Number of pages7
JournalChemistry - A European Journal
Volume19
Issue number19
DOIs
StatePublished - 3 May 2013
Externally publishedYes

Keywords

  • electrochemical capacitors
  • electrochemical performance
  • electrochemistry
  • electrospinning
  • nanostructures
  • porous NiCoO nanotubes

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