Enantiomerically pure lanthanide-organic polytungstates exhibiting two-photon absorption properties

Wei Wei Ju; Hai Tao Zhang; Xiao Xu; Yu Zhang; Yan Xu

doi:10.1021/ic500157x

Enantiomerically pure lanthanide-organic polytungstates exhibiting two-photon absorption properties

Wei Wei Ju, Hai Tao Zhang, Xiao Xu, Yu Zhang, Yan Xu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

Two enantiomerically pure polytungstates, Na₂[(CH ₃)₂NH₂]₃{Na[Ce^III(H ₂O)(CH₃CH₂OH)(l-tartH₃)(H ₂Si₂W₁₉O₆₆)]}·3.5H ₂O (l-1) and [(CH₃)₂NH₂] ₇{Na[Ce^III(H₂O)(CH₃CH ₂OH)(d-tartH₃)(Si₂W₁₉O ₆₆)]}·2.5H₂O (d-1), were successfully synthesized. Structural analysis indicates that chiral tartrate ligands directly connect with novel lacunary [Si₂W₁₉O₆₆]^10- polytungstate units. Strong induced optical activity in the polyoxometalate (POM) units is manifested by circular dichroism spectroscopy. Z-scan analysis revealed that l-1 and d-1 are the first chiral POM-based complexes that exhibit two-photon absorption properties typical of the third-order nonlinear optical response.

Original language	English
Pages (from-to)	3269-3271
Number of pages	3
Journal	Inorganic Chemistry
Volume	53
Issue number	7
DOIs	https://doi.org/10.1021/ic500157x
State	Published - 7 Apr 2014

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title = "Enantiomerically pure lanthanide-organic polytungstates exhibiting two-photon absorption properties",

abstract = "Two enantiomerically pure polytungstates, Na2[(CH 3)2NH2]3{Na[CeIII(H 2O)(CH3CH2OH)(l-tartH3)(H 2Si2W19O66)]}·3.5H 2O (l-1) and [(CH3)2NH2] 7{Na[CeIII(H2O)(CH3CH 2OH)(d-tartH3)(Si2W19O 66)]}·2.5H2O (d-1), were successfully synthesized. Structural analysis indicates that chiral tartrate ligands directly connect with novel lacunary [Si2W19O66]10- polytungstate units. Strong induced optical activity in the polyoxometalate (POM) units is manifested by circular dichroism spectroscopy. Z-scan analysis revealed that l-1 and d-1 are the first chiral POM-based complexes that exhibit two-photon absorption properties typical of the third-order nonlinear optical response.",

author = "Ju, {Wei Wei} and Zhang, {Hai Tao} and Xiao Xu and Yu Zhang and Yan Xu",

year = "2014",

month = apr,

day = "7",

doi = "10.1021/ic500157x",

language = "英语",

volume = "53",

pages = "3269--3271",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Enantiomerically pure lanthanide-organic polytungstates exhibiting two-photon absorption properties

AU - Ju, Wei Wei

AU - Zhang, Hai Tao

AU - Xu, Xiao

AU - Zhang, Yu

AU - Xu, Yan

PY - 2014/4/7

Y1 - 2014/4/7

N2 - Two enantiomerically pure polytungstates, Na2[(CH 3)2NH2]3{Na[CeIII(H 2O)(CH3CH2OH)(l-tartH3)(H 2Si2W19O66)]}·3.5H 2O (l-1) and [(CH3)2NH2] 7{Na[CeIII(H2O)(CH3CH 2OH)(d-tartH3)(Si2W19O 66)]}·2.5H2O (d-1), were successfully synthesized. Structural analysis indicates that chiral tartrate ligands directly connect with novel lacunary [Si2W19O66]10- polytungstate units. Strong induced optical activity in the polyoxometalate (POM) units is manifested by circular dichroism spectroscopy. Z-scan analysis revealed that l-1 and d-1 are the first chiral POM-based complexes that exhibit two-photon absorption properties typical of the third-order nonlinear optical response.

AB - Two enantiomerically pure polytungstates, Na2[(CH 3)2NH2]3{Na[CeIII(H 2O)(CH3CH2OH)(l-tartH3)(H 2Si2W19O66)]}·3.5H 2O (l-1) and [(CH3)2NH2] 7{Na[CeIII(H2O)(CH3CH 2OH)(d-tartH3)(Si2W19O 66)]}·2.5H2O (d-1), were successfully synthesized. Structural analysis indicates that chiral tartrate ligands directly connect with novel lacunary [Si2W19O66]10- polytungstate units. Strong induced optical activity in the polyoxometalate (POM) units is manifested by circular dichroism spectroscopy. Z-scan analysis revealed that l-1 and d-1 are the first chiral POM-based complexes that exhibit two-photon absorption properties typical of the third-order nonlinear optical response.

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U2 - 10.1021/ic500157x

DO - 10.1021/ic500157x

M3 - 文章

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AN - SCOPUS:84897988799

SN - 0020-1669

VL - 53

SP - 3269

EP - 3271

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Enantiomerically pure lanthanide-organic polytungstates exhibiting two-photon absorption properties

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