Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes

Jun Lu; Mei Ling Hong; Shun Jun Ji; Yong Chua Teo; Teck Peng Loh

doi:10.1039/b507768k

Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes

Jun Lu, Mei Ling Hong, Shun Jun Ji, Yong Chua Teo, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)₃ and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54-95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.

Original language	English
Pages (from-to)	4217-4218
Number of pages	2
Journal	Chemical Communications
Issue number	33
DOIs	https://doi.org/10.1039/b507768k
State	Published - 7 Sep 2005
Externally published	Yes

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title = "Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes",

abstract = "In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54-95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.",

author = "Jun Lu and Hong, {Mei Ling} and Ji, {Shun Jun} and Teo, {Yong Chua} and Loh, {Teck Peng}",

year = "2005",

month = sep,

day = "7",

doi = "10.1039/b507768k",

language = "英语",

pages = "4217--4218",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "33",

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T1 - Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes

AU - Lu, Jun

AU - Hong, Mei Ling

AU - Ji, Shun Jun

AU - Teo, Yong Chua

AU - Loh, Teck Peng

PY - 2005/9/7

Y1 - 2005/9/7

N2 - In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54-95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.

AB - In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54-95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.

UR - http://www.scopus.com/inward/record.url?scp=25144446723&partnerID=8YFLogxK

U2 - 10.1039/b507768k

DO - 10.1039/b507768k

M3 - 文章

AN - SCOPUS:25144446723

SN - 1359-7345

SP - 4217

EP - 4218

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes

Abstract

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