Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex

Jun Lu; Mei Ling Hong; Shun Jun Ji; Teck Peng Loh

doi:10.1039/b415550e

Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex

Jun Lu, Mei Ling Hong, Shun Jun Ji, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)₃ and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioseleetivities (60-93% ee).

Original language	English
Pages (from-to)	1010-1012
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b415550e
State	Published - 28 Feb 2005
Externally published	Yes

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@article{69e431a634434e75aad77b12fb639d1d,

title = "Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex",

abstract = "In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioseleetivities (60-93% ee).",

author = "Jun Lu and Hong, {Mei Ling} and Ji, {Shun Jun} and Loh, {Teck Peng}",

year = "2005",

month = feb,

day = "28",

doi = "10.1039/b415550e",

language = "英语",

pages = "1010--1012",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "8",

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TY - JOUR

T1 - Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex

AU - Lu, Jun

AU - Hong, Mei Ling

AU - Ji, Shun Jun

AU - Loh, Teck Peng

PY - 2005/2/28

Y1 - 2005/2/28

N2 - In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioseleetivities (60-93% ee).

AB - In the presence of 20 mol% of a chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with aldehydes to afford the corresponding homoallylic alcohols in moderate to high enantioseleetivities (60-93% ee).

UR - http://www.scopus.com/inward/record.url?scp=14944385284&partnerID=8YFLogxK

U2 - 10.1039/b415550e

DO - 10.1039/b415550e

M3 - 文章

C2 - 15719099

AN - SCOPUS:14944385284

SN - 1359-7345

SP - 1010

EP - 1012

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Enantioselective synthesis of homoallylic alcohols via a chiral In(III)-PYBOX complex

Abstract

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