Enhanced piezocatalytic hydrogen evolution performance of bismuth vanadate by the synergistic effect of facet engineering and cocatalyst engineering

Developing piezocatalysts with excellent piezocatalytic hydrogen evolution reaction (HER) performance is highly desired but also challenging. Here, facet engineering and cocatalyst engineering are employed to synergistically improve the piezocatalytic HER efficiency of BiVO₄ (BVO). Monoclinic BVO catalysts with distinct exposed facets are synthesized by adjusting pH of hydrothermal reaction. The BVO with highly exposed {1 1 0} facet exhibits a superior piezocatalytic HER performance (617.9 μmol g^-1h⁻¹) compared with that with {0 1 0} facet, owing to the strong piezoelectric property, high charge transfer efficiency, and excellent hydrogen adsorption/desorption capacity. The HER efficiency is enhanced by 44.7% by selectively depositing cocatalyst of Ag nanoparticles specifically on the reductive {0 1 0} facet of BVO, where the Ag-BVO interface provides the directional electron transport for high-efficiency charge separation. Under the collaboration between cocatalyst of CoO_x on {1 1 0} facet and the hole sacrificial agent of methanol, the piezocatalytic HER efficiency is evidently enhanced by 2 times because CoO_x and methanol can impede the water oxidation and improve the charge separation. This easy and simple strategy provides an alternative perspective on designing high-performance piezocatalysts.