Excess molar enthalpies of methyl tert-butyl ether + (cyclohexane or 2,3-dimethylbutane) + n-decane ternary mixtures at 298.15 K

Shemin Zhu, Shubao Shen, George C. Benson, B. C.Y. Lu

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Abstract

Microcalorimetric measurements of the excess molar enthalpies at 298.15 K are reported for the ternary mixtures methyl tert-butyl ether + (cyclohexane or 2,3-dimethylbutane) + n-decane. Smooth representations of the results are presented and used to construct constant enthalpy contours on a Roozeboom diagram. Application of the Flory theory of mixtures to estimate the enthalpies of the ternary mixtures from analyses of data for their constituent binaries is also described.

Original languageEnglish
Pages (from-to)161-169
Number of pages9
JournalThermochimica Acta
Volume235
Issue number2
DOIs
StatePublished - 21 Apr 1994
Externally publishedYes

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