Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu2+ ions

Xin Wang; Tao Qin; Song Song Bao; Yu Chi Zhang; Xuan Shen; Li Min Zheng; Dunru Zhu

doi:10.1039/c6ta06792a

Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu²⁺ ions

Xin Wang, Tao Qin, Song Song Bao, Yu Chi Zhang, Xuan Shen, Li Min Zheng, Dunru Zhu

COLLEGE OF CHEMICAL ENGINEERING

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Abstract

The development of cost-effective proton-conducting materials with high conductivity and water stability is currently of great interest in fuel-cell technology. By using a simple aqueous solution method, a water stable 3D Eu-MOF material, [Me₂NH₂][Eu(ox)₂(H₂O)]·3H₂O (1), can be easily synthesized from oxalic acid (H₂ox) and Eu(NO₃)₃·6H₂O on a large scale. 1 possesses a dia net topology and an extensive hydrogen-bonded network consisting of dimethyl ammonium and water molecules in 1D channels. 1 shows a high proton conductivity of 2.73 × 10^-3 S cm^-1 at 55 °C and 95% relative humidity, and it is used as a sensitive luminescent sensor for Cu²⁺ ions in aqueous solutions.

Original language	English
Pages (from-to)	16484-16489
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	4
Issue number	42
DOIs	https://doi.org/10.1039/c6ta06792a
State	Published - 2016

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title = "Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu2+ ions",

abstract = "The development of cost-effective proton-conducting materials with high conductivity and water stability is currently of great interest in fuel-cell technology. By using a simple aqueous solution method, a water stable 3D Eu-MOF material, [Me2NH2][Eu(ox)2(H2O)]·3H2O (1), can be easily synthesized from oxalic acid (H2ox) and Eu(NO3)3·6H2O on a large scale. 1 possesses a dia net topology and an extensive hydrogen-bonded network consisting of dimethyl ammonium and water molecules in 1D channels. 1 shows a high proton conductivity of 2.73 × 10-3 S cm-1 at 55 °C and 95% relative humidity, and it is used as a sensitive luminescent sensor for Cu2+ ions in aqueous solutions.",

author = "Xin Wang and Tao Qin and Bao, {Song Song} and Zhang, {Yu Chi} and Xuan Shen and Zheng, {Li Min} and Dunru Zhu",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ta06792a",

language = "英语",

volume = "4",

pages = "16484--16489",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu2+ ions

AU - Wang, Xin

AU - Qin, Tao

AU - Bao, Song Song

AU - Zhang, Yu Chi

AU - Shen, Xuan

AU - Zheng, Li Min

AU - Zhu, Dunru

PY - 2016

Y1 - 2016

N2 - The development of cost-effective proton-conducting materials with high conductivity and water stability is currently of great interest in fuel-cell technology. By using a simple aqueous solution method, a water stable 3D Eu-MOF material, [Me2NH2][Eu(ox)2(H2O)]·3H2O (1), can be easily synthesized from oxalic acid (H2ox) and Eu(NO3)3·6H2O on a large scale. 1 possesses a dia net topology and an extensive hydrogen-bonded network consisting of dimethyl ammonium and water molecules in 1D channels. 1 shows a high proton conductivity of 2.73 × 10-3 S cm-1 at 55 °C and 95% relative humidity, and it is used as a sensitive luminescent sensor for Cu2+ ions in aqueous solutions.

AB - The development of cost-effective proton-conducting materials with high conductivity and water stability is currently of great interest in fuel-cell technology. By using a simple aqueous solution method, a water stable 3D Eu-MOF material, [Me2NH2][Eu(ox)2(H2O)]·3H2O (1), can be easily synthesized from oxalic acid (H2ox) and Eu(NO3)3·6H2O on a large scale. 1 possesses a dia net topology and an extensive hydrogen-bonded network consisting of dimethyl ammonium and water molecules in 1D channels. 1 shows a high proton conductivity of 2.73 × 10-3 S cm-1 at 55 °C and 95% relative humidity, and it is used as a sensitive luminescent sensor for Cu2+ ions in aqueous solutions.

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U2 - 10.1039/c6ta06792a

DO - 10.1039/c6ta06792a

M3 - 文章

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SN - 2050-7488

VL - 4

SP - 16484

EP - 16489

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 42

ER -

Facile synthesis of a water stable 3D Eu-MOF showing high proton conductivity and its application as a sensitive luminescent sensor for Cu²⁺ ions

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