Facile synthesis of spherical V-MCM-48

Xiao Ying Xu; Yan Kong; Yu Chen; Nan Zhao; Xiao Bo Shi; Jun Wang

Facile synthesis of spherical V-MCM-48

Xiao Ying Xu, Yan Kong, Yu Chen, Nan Zhao, Xiao Bo Shi, Jun Wang

COLLEGE OF CHEMICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Spherical V-MCM-48 was synthesized by one-step hydrothermal method under low template concentration using ethanol as the co-solvent. The materials were characterized by XRD, FS-SEM, N ₂ adsorption, FTIR, Raman, NMR, XPS and ICP. The results show that the materials are with high specific surface area (1005 m ².g ^-1), ordered malodorous structure and spherical morphology. V ₂O ₅ crystal is not found when the V/Si molar ratio is 2.91%. Most of vanadium is incorporated to the framework of silica. The materials are effective catalysts in the oxidation of the styrene with H ₂O ₂ under low temperature.

Original language	English
Pages (from-to)	2478-2484
Number of pages	7
Journal	Chinese Journal of Inorganic Chemistry
Volume	28
Issue number	11
State	Published - 2012

Keywords

Spherical morphology
Styrene oxidation
Synthesis
V-MCM-48

Cite this

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title = "Facile synthesis of spherical V-MCM-48",

abstract = "Spherical V-MCM-48 was synthesized by one-step hydrothermal method under low template concentration using ethanol as the co-solvent. The materials were characterized by XRD, FS-SEM, N 2 adsorption, FTIR, Raman, NMR, XPS and ICP. The results show that the materials are with high specific surface area (1005 m 2.g -1), ordered malodorous structure and spherical morphology. V 2O 5 crystal is not found when the V/Si molar ratio is 2.91%. Most of vanadium is incorporated to the framework of silica. The materials are effective catalysts in the oxidation of the styrene with H 2O 2 under low temperature.",

keywords = "Spherical morphology, Styrene oxidation, Synthesis, V-MCM-48",

author = "Xu, {Xiao Ying} and Yan Kong and Yu Chen and Nan Zhao and Shi, {Xiao Bo} and Jun Wang",

year = "2012",

language = "英语",

volume = "28",

pages = "2478--2484",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "11",

}

TY - JOUR

T1 - Facile synthesis of spherical V-MCM-48

AU - Xu, Xiao Ying

AU - Kong, Yan

AU - Chen, Yu

AU - Zhao, Nan

AU - Shi, Xiao Bo

AU - Wang, Jun

PY - 2012

Y1 - 2012

N2 - Spherical V-MCM-48 was synthesized by one-step hydrothermal method under low template concentration using ethanol as the co-solvent. The materials were characterized by XRD, FS-SEM, N 2 adsorption, FTIR, Raman, NMR, XPS and ICP. The results show that the materials are with high specific surface area (1005 m 2.g -1), ordered malodorous structure and spherical morphology. V 2O 5 crystal is not found when the V/Si molar ratio is 2.91%. Most of vanadium is incorporated to the framework of silica. The materials are effective catalysts in the oxidation of the styrene with H 2O 2 under low temperature.

AB - Spherical V-MCM-48 was synthesized by one-step hydrothermal method under low template concentration using ethanol as the co-solvent. The materials were characterized by XRD, FS-SEM, N 2 adsorption, FTIR, Raman, NMR, XPS and ICP. The results show that the materials are with high specific surface area (1005 m 2.g -1), ordered malodorous structure and spherical morphology. V 2O 5 crystal is not found when the V/Si molar ratio is 2.91%. Most of vanadium is incorporated to the framework of silica. The materials are effective catalysts in the oxidation of the styrene with H 2O 2 under low temperature.

KW - Spherical morphology

KW - Styrene oxidation

KW - Synthesis

KW - V-MCM-48

UR - http://www.scopus.com/inward/record.url?scp=84868154702&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:84868154702

SN - 1001-4861

VL - 28

SP - 2478

EP - 2484

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 11

ER -

Facile synthesis of spherical V-MCM-48

Abstract

Keywords

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