Form-stable phase change nanocomposites for thermal energy storage based on hypercrosslinked polymer nanospheres

Xiaohui Fu; Yunfei Liu; Xiaowei Jiang; Qiuliang Wang; Yali Luo; Yinong Lyu

doi:10.1016/j.tca.2018.05.005

Form-stable phase change nanocomposites for thermal energy storage based on hypercrosslinked polymer nanospheres

Xiaohui Fu, Yunfei Liu, Xiaowei Jiang, Qiuliang Wang, Yali Luo, Yinong Lyu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Two kinds of hypercrosslinked polymer nanospheres (HCPNs), which were synthesized via Friedel-Crafts and Scholl coupling reactions, were used as porous matrix to prepare form-stable phase change materials nanocomposites (HCPNs-PCMs). Owing to the large BET surface area and the strong hydrophobicity of HCPNs, PCMs (palmitic acid and 1-octadecanol) can be absorbed spontaneously into HCPNs. The properties of HCPNs-PCMs have been characterized via scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The DSC results showed that the HCPNs-PCMs had latent heats of 111.8−134.9 J g⁻¹. The mass fraction of PCMs in HCPNs-PCMs ranged from 71.4 wt% to 74.5 wt%. After 300 melting and freezing cycles, the nanocomposites maintained their phase transition properties perfectly, indicating excellent recyclability and high thermal stability.

Original language	English
Pages (from-to)	111-118
Number of pages	8
Journal	Thermochimica Acta
Volume	665
DOIs	https://doi.org/10.1016/j.tca.2018.05.005
State	Published - 10 Jul 2018

Keywords

Hypercrosslinked polymer nanospheres
Nanocomposite
Phase change material
Thermal energy storage

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title = "Form-stable phase change nanocomposites for thermal energy storage based on hypercrosslinked polymer nanospheres",

abstract = "Two kinds of hypercrosslinked polymer nanospheres (HCPNs), which were synthesized via Friedel-Crafts and Scholl coupling reactions, were used as porous matrix to prepare form-stable phase change materials nanocomposites (HCPNs-PCMs). Owing to the large BET surface area and the strong hydrophobicity of HCPNs, PCMs (palmitic acid and 1-octadecanol) can be absorbed spontaneously into HCPNs. The properties of HCPNs-PCMs have been characterized via scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The DSC results showed that the HCPNs-PCMs had latent heats of 111.8−134.9 J g−1. The mass fraction of PCMs in HCPNs-PCMs ranged from 71.4 wt% to 74.5 wt%. After 300 melting and freezing cycles, the nanocomposites maintained their phase transition properties perfectly, indicating excellent recyclability and high thermal stability.",

keywords = "Hypercrosslinked polymer nanospheres, Nanocomposite, Phase change material, Thermal energy storage",

author = "Xiaohui Fu and Yunfei Liu and Xiaowei Jiang and Qiuliang Wang and Yali Luo and Yinong Lyu",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = jul,

day = "10",

doi = "10.1016/j.tca.2018.05.005",

language = "英语",

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T1 - Form-stable phase change nanocomposites for thermal energy storage based on hypercrosslinked polymer nanospheres

AU - Fu, Xiaohui

AU - Liu, Yunfei

AU - Jiang, Xiaowei

AU - Wang, Qiuliang

AU - Luo, Yali

AU - Lyu, Yinong

PY - 2018/7/10

Y1 - 2018/7/10

N2 - Two kinds of hypercrosslinked polymer nanospheres (HCPNs), which were synthesized via Friedel-Crafts and Scholl coupling reactions, were used as porous matrix to prepare form-stable phase change materials nanocomposites (HCPNs-PCMs). Owing to the large BET surface area and the strong hydrophobicity of HCPNs, PCMs (palmitic acid and 1-octadecanol) can be absorbed spontaneously into HCPNs. The properties of HCPNs-PCMs have been characterized via scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The DSC results showed that the HCPNs-PCMs had latent heats of 111.8−134.9 J g−1. The mass fraction of PCMs in HCPNs-PCMs ranged from 71.4 wt% to 74.5 wt%. After 300 melting and freezing cycles, the nanocomposites maintained their phase transition properties perfectly, indicating excellent recyclability and high thermal stability.

AB - Two kinds of hypercrosslinked polymer nanospheres (HCPNs), which were synthesized via Friedel-Crafts and Scholl coupling reactions, were used as porous matrix to prepare form-stable phase change materials nanocomposites (HCPNs-PCMs). Owing to the large BET surface area and the strong hydrophobicity of HCPNs, PCMs (palmitic acid and 1-octadecanol) can be absorbed spontaneously into HCPNs. The properties of HCPNs-PCMs have been characterized via scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The DSC results showed that the HCPNs-PCMs had latent heats of 111.8−134.9 J g−1. The mass fraction of PCMs in HCPNs-PCMs ranged from 71.4 wt% to 74.5 wt%. After 300 melting and freezing cycles, the nanocomposites maintained their phase transition properties perfectly, indicating excellent recyclability and high thermal stability.

KW - Hypercrosslinked polymer nanospheres

KW - Nanocomposite

KW - Phase change material

KW - Thermal energy storage

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U2 - 10.1016/j.tca.2018.05.005

DO - 10.1016/j.tca.2018.05.005

M3 - 文章

AN - SCOPUS:85047607885

SN - 0040-6031

VL - 665

SP - 111

EP - 118

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

Form-stable phase change nanocomposites for thermal energy storage based on hypercrosslinked polymer nanospheres

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Keywords

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