Four 2D "fully reduced" polyoxovanadates: Vanadium oxide clusters encapsulating different guest molecules

Hongxiang Wan; Congling Wang; Yu Zhang; Hao Miao; Shuai Zhou; Yan Xu

doi:10.1021/ic501573p

Four 2D "fully reduced" polyoxovanadates: Vanadium oxide clusters encapsulating different guest molecules

Hongxiang Wan, Congling Wang, Yu Zhang, Hao Miao, Shuai Zhou, Yan Xu

College of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Four two-dimensional fully reduced polyoxovanadates, namely, [Cd(DAP)₂]₄[HV^III₃V^IV₁₈P₆O₆₀(DAP)₃(HOCH₂CH₂OH)]·10H₂O (1), [Cd(DAP)₂]₄[HV^III₃V^IV₁₈P₆O₆₀(DAP)₃(CH₃OH)]·11H₂O (2), [Cd(DAP)₂]₄[HV^III₃V^IV₁₈P₆O₆₀(DAP)₃(CH₃CH₂OH)]·4H₂O (3) and Co^III(DAP)₃[Co^II(DAP)₂]₃[V^III₃V^IV₁₈P₆O₆₀(DAP)₃(HOCH₂CH₂OH)]·14H₂O (4) were synthesized by virtue of the reducing power of alkylamine in hydrothermal conditions. Single-crystal X-ray structural analysis, magnetic measurement, IR spectroscopy, elemental analysis, and thermogravimetric measurements were performed to analyze the structures and properties of these four compounds. Structural analysis indicates that the four compounds contain the same huge low-valent vanadium oxide anion cages [V^III₃V^IV₁₈P₆O₆₀(DAP)₃]^9-, and the cages can catch different guest molecules. Four cages are linked by Co or Cd atoms to form a four-membered ring, while adjacent four-membered rings are connected to each other by sharing edges to make an inorganic-organic hybrid layer. The magnetic susceptibility measurements of four compounds indicate ferrimagnetic interactions between vanadium ions.

Original language	English
Pages (from-to)	10498-10505
Number of pages	8
Journal	Inorganic Chemistry
Volume	53
Issue number	19
DOIs	https://doi.org/10.1021/ic501573p
State	Published - 6 Oct 2014

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title = "Four 2D {"}fully reduced{"} polyoxovanadates: Vanadium oxide clusters encapsulating different guest molecules",

abstract = "Four two-dimensional fully reduced polyoxovanadates, namely, [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·10H2O (1), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3OH)]·11H2O (2), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3CH2OH)]·4H2O (3) and CoIII(DAP)3[CoII(DAP)2]3[VIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·14H2O (4) were synthesized by virtue of the reducing power of alkylamine in hydrothermal conditions. Single-crystal X-ray structural analysis, magnetic measurement, IR spectroscopy, elemental analysis, and thermogravimetric measurements were performed to analyze the structures and properties of these four compounds. Structural analysis indicates that the four compounds contain the same huge low-valent vanadium oxide anion cages [VIII3VIV18P6O60(DAP)3]9-, and the cages can catch different guest molecules. Four cages are linked by Co or Cd atoms to form a four-membered ring, while adjacent four-membered rings are connected to each other by sharing edges to make an inorganic-organic hybrid layer. The magnetic susceptibility measurements of four compounds indicate ferrimagnetic interactions between vanadium ions.",

author = "Hongxiang Wan and Congling Wang and Yu Zhang and Hao Miao and Shuai Zhou and Yan Xu",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

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T1 - Four 2D "fully reduced" polyoxovanadates

T2 - Vanadium oxide clusters encapsulating different guest molecules

AU - Wan, Hongxiang

AU - Wang, Congling

AU - Zhang, Yu

AU - Miao, Hao

AU - Zhou, Shuai

AU - Xu, Yan

PY - 2014/10/6

Y1 - 2014/10/6

N2 - Four two-dimensional fully reduced polyoxovanadates, namely, [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·10H2O (1), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3OH)]·11H2O (2), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3CH2OH)]·4H2O (3) and CoIII(DAP)3[CoII(DAP)2]3[VIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·14H2O (4) were synthesized by virtue of the reducing power of alkylamine in hydrothermal conditions. Single-crystal X-ray structural analysis, magnetic measurement, IR spectroscopy, elemental analysis, and thermogravimetric measurements were performed to analyze the structures and properties of these four compounds. Structural analysis indicates that the four compounds contain the same huge low-valent vanadium oxide anion cages [VIII3VIV18P6O60(DAP)3]9-, and the cages can catch different guest molecules. Four cages are linked by Co or Cd atoms to form a four-membered ring, while adjacent four-membered rings are connected to each other by sharing edges to make an inorganic-organic hybrid layer. The magnetic susceptibility measurements of four compounds indicate ferrimagnetic interactions between vanadium ions.

AB - Four two-dimensional fully reduced polyoxovanadates, namely, [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·10H2O (1), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3OH)]·11H2O (2), [Cd(DAP)2]4[HVIII3VIV18P6O60(DAP)3(CH3CH2OH)]·4H2O (3) and CoIII(DAP)3[CoII(DAP)2]3[VIII3VIV18P6O60(DAP)3(HOCH2CH2OH)]·14H2O (4) were synthesized by virtue of the reducing power of alkylamine in hydrothermal conditions. Single-crystal X-ray structural analysis, magnetic measurement, IR spectroscopy, elemental analysis, and thermogravimetric measurements were performed to analyze the structures and properties of these four compounds. Structural analysis indicates that the four compounds contain the same huge low-valent vanadium oxide anion cages [VIII3VIV18P6O60(DAP)3]9-, and the cages can catch different guest molecules. Four cages are linked by Co or Cd atoms to form a four-membered ring, while adjacent four-membered rings are connected to each other by sharing edges to make an inorganic-organic hybrid layer. The magnetic susceptibility measurements of four compounds indicate ferrimagnetic interactions between vanadium ions.

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U2 - 10.1021/ic501573p

DO - 10.1021/ic501573p

M3 - 文章

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SN - 0020-1669

VL - 53

SP - 10498

EP - 10505

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Four 2D "fully reduced" polyoxovanadates: Vanadium oxide clusters encapsulating different guest molecules

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