TY - JOUR
T1 - High promoting of selective oxidation of ethylbenzene by Mn-ZSM-5 synthesized without organic template and calcination
AU - Liu, Xianfeng
AU - Gao, Shuying
AU - Yang, Fu
AU - Zhou, Shijian
AU - Kong, Yan
N1 - Publisher Copyright:
© 2020, Springer Nature B.V.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - Abstract: Acetophenone is a valuable and widely applied intermediate in chemical industry, but limited by the synthesis with low-cost and efficient heterogeneous catalyst. Herein, we report tetrahedral coordination manganese-incorporated ZSM-5 zeolite (Mn-ZSM-5) by three steps involving acid hydrolysis of Mn(NO3)2 with tetraethylorthosilicate, basic aging and hydrothermal crystallization without organic template and calcination. Mn-ZSM-5 was identified by characterizations such as X-ray diffraction, Fourier transform infrared spectra (FTIR), field emission scanning electron microscopy, inductively coupling plasma spectrometer, N2-adsorption/desorption and FTIR, X-ray photoelectron spectroscopy (XPS), electron spin-resonance spectroscopy (ESR), NH3-TPD and H2-TPR. Moreover, tetrahedral coordination Mn atoms successfully incorporate into the framework of ZSM-5 demonstrated by ESR and XPS spectra. Furthermore, Mn-ZSM-5 with high crystallinity performs high and stable catalytic activity in the oxidation of ethylbenzene owing to tetrahedral Mn3+ in the framework of ZSM-5 as catalytic active sites. Graphic abstract: Tetrahedral coordination manganese-incorporated ZSM-5 zeolites synthesized without organic template and calcination performed high and stable catalytic activity on the oxidation of ethylbenzene owing to tetrahedral Mn3+ as catalytic active sites.[Figure not available: see fulltext.]
AB - Abstract: Acetophenone is a valuable and widely applied intermediate in chemical industry, but limited by the synthesis with low-cost and efficient heterogeneous catalyst. Herein, we report tetrahedral coordination manganese-incorporated ZSM-5 zeolite (Mn-ZSM-5) by three steps involving acid hydrolysis of Mn(NO3)2 with tetraethylorthosilicate, basic aging and hydrothermal crystallization without organic template and calcination. Mn-ZSM-5 was identified by characterizations such as X-ray diffraction, Fourier transform infrared spectra (FTIR), field emission scanning electron microscopy, inductively coupling plasma spectrometer, N2-adsorption/desorption and FTIR, X-ray photoelectron spectroscopy (XPS), electron spin-resonance spectroscopy (ESR), NH3-TPD and H2-TPR. Moreover, tetrahedral coordination Mn atoms successfully incorporate into the framework of ZSM-5 demonstrated by ESR and XPS spectra. Furthermore, Mn-ZSM-5 with high crystallinity performs high and stable catalytic activity in the oxidation of ethylbenzene owing to tetrahedral Mn3+ in the framework of ZSM-5 as catalytic active sites. Graphic abstract: Tetrahedral coordination manganese-incorporated ZSM-5 zeolites synthesized without organic template and calcination performed high and stable catalytic activity on the oxidation of ethylbenzene owing to tetrahedral Mn3+ as catalytic active sites.[Figure not available: see fulltext.]
KW - Acetophenone
KW - Manganese
KW - Selective oxidation
KW - Template-free
KW - ZSM-5
UR - http://www.scopus.com/inward/record.url?scp=85082069499&partnerID=8YFLogxK
U2 - 10.1007/s11164-020-04123-w
DO - 10.1007/s11164-020-04123-w
M3 - 文章
AN - SCOPUS:85082069499
SN - 0922-6168
VL - 46
SP - 2817
EP - 2832
JO - Research on Chemical Intermediates
JF - Research on Chemical Intermediates
IS - 5
ER -