TY - JOUR
T1 - Higher Symmetry Multinuclear Clusters of Metal-Organic Frameworks for Highly Selective CO 2 Capture
AU - Jiang, Jingjing
AU - Lu, Zhiyong
AU - Zhang, Mingxing
AU - Duan, Jingui
AU - Zhang, Wenwei
AU - Pan, Yi
AU - Bai, Junfeng
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/12/26
Y1 - 2018/12/26
N2 - A new approach of finely tuning multinuclear clusters of metal-organic frameworks (MOFs) through symmetry-upgradingly isoreticular transformation was first presented and a bcu-type MOF, {[Cu 4 (μ 4 -O)Cl 2 (IN) 4 ][CuCl 2 ]} ∞ (NJU-Bai35; NJU-Bai for Nanjing University Bai group), with cluster [Cu 4 (μ 4 -O)Cl 2 (COO) 4 N 4 ] of higher symmetry compared to the pristine MOF, was successfully synthesized. The symmetry upgrading implemented on the inorganic part triggers the adjustment of channels in NJU-Bai35 to fit CO 2 molecules, leading to a high CO 2 adsorption capacity (7.20 wt % at ∼0.15 bar and 298 K) and high selectivity of CO 2 over N 2 and CH 4 (275.8 for CO 2 /N 2 and 11.6 for CO 2 /CH 4 ) in NJU-Bai35. Breakthrough experiments further confirmed that NJU-Bai35 might be an excellent candidate for CO 2 capture and natural gas purification.
AB - A new approach of finely tuning multinuclear clusters of metal-organic frameworks (MOFs) through symmetry-upgradingly isoreticular transformation was first presented and a bcu-type MOF, {[Cu 4 (μ 4 -O)Cl 2 (IN) 4 ][CuCl 2 ]} ∞ (NJU-Bai35; NJU-Bai for Nanjing University Bai group), with cluster [Cu 4 (μ 4 -O)Cl 2 (COO) 4 N 4 ] of higher symmetry compared to the pristine MOF, was successfully synthesized. The symmetry upgrading implemented on the inorganic part triggers the adjustment of channels in NJU-Bai35 to fit CO 2 molecules, leading to a high CO 2 adsorption capacity (7.20 wt % at ∼0.15 bar and 298 K) and high selectivity of CO 2 over N 2 and CH 4 (275.8 for CO 2 /N 2 and 11.6 for CO 2 /CH 4 ) in NJU-Bai35. Breakthrough experiments further confirmed that NJU-Bai35 might be an excellent candidate for CO 2 capture and natural gas purification.
UR - http://www.scopus.com/inward/record.url?scp=85053841893&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b07589
DO - 10.1021/jacs.8b07589
M3 - 文章
C2 - 30223654
AN - SCOPUS:85053841893
SN - 0002-7863
VL - 140
SP - 17825
EP - 17829
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 51
ER -