Highly efficient and selective reduction of nitroarenes with hydrazine over supported rhodium nanoparticles

Pingfei Luo; Kunling Xu; Rui Zhang; Lei Huang; Jun Wang; Weihong Xing; Jun Huang

doi:10.1039/c1cy00358e

Highly efficient and selective reduction of nitroarenes with hydrazine over supported rhodium nanoparticles

Pingfei Luo, Kunling Xu, Rui Zhang, Lei Huang, Jun Wang, Weihong Xing, Jun Huang

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

A highly efficient and selective Rh nanocatalyst was demonstrated for the reduction of nitroarenes with hydrazine monohydrate under mild conditions. Functional groups such as halides (F, Cl, Br and I), CN, NH ₂, OH, alkene, ester and amide groups were untouched during the hydrogenation of the nitroarenes, and the corresponding anilines were obtained quantitatively.

Original language	English
Pages (from-to)	301-304
Number of pages	4
Journal	Catalysis Science and Technology
Volume	2
Issue number	2
DOIs	https://doi.org/10.1039/c1cy00358e
State	Published - Feb 2012

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abstract = "A highly efficient and selective Rh nanocatalyst was demonstrated for the reduction of nitroarenes with hydrazine monohydrate under mild conditions. Functional groups such as halides (F, Cl, Br and I), CN, NH 2, OH, alkene, ester and amide groups were untouched during the hydrogenation of the nitroarenes, and the corresponding anilines were obtained quantitatively.",

author = "Pingfei Luo and Kunling Xu and Rui Zhang and Lei Huang and Jun Wang and Weihong Xing and Jun Huang",

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AU - Luo, Pingfei

AU - Xu, Kunling

AU - Zhang, Rui

AU - Huang, Lei

AU - Wang, Jun

AU - Xing, Weihong

AU - Huang, Jun

PY - 2012/2

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AB - A highly efficient and selective Rh nanocatalyst was demonstrated for the reduction of nitroarenes with hydrazine monohydrate under mild conditions. Functional groups such as halides (F, Cl, Br and I), CN, NH 2, OH, alkene, ester and amide groups were untouched during the hydrogenation of the nitroarenes, and the corresponding anilines were obtained quantitatively.

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Highly efficient and selective reduction of nitroarenes with hydrazine over supported rhodium nanoparticles

Abstract

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