Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

Changchang Zou; Qianqian Li; Fujun Cheng; Haijun Wang; Jingui Duan; Wanqin Jin

doi:10.1039/c7ce00522a

Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

Changchang Zou, Qianqian Li, Fujun Cheng, Haijun Wang, Jingui Duan, Wanqin Jin

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of l-/d-alanine and Zn(CH₃COO)₂·2H₂O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP d-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.

Original language	English
Pages (from-to)	2718-2722
Number of pages	5
Journal	CrystEngComm
Volume	19
Issue number	20
DOIs	https://doi.org/10.1039/c7ce00522a
State	Published - 2017

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title = "Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation",

abstract = "A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of l-/d-alanine and Zn(CH3COO)2·2H2O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP d-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.",

author = "Changchang Zou and Qianqian Li and Fujun Cheng and Haijun Wang and Jingui Duan and Wanqin Jin",

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T1 - Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

AU - Zou, Changchang

AU - Li, Qianqian

AU - Cheng, Fujun

AU - Wang, Haijun

AU - Duan, Jingui

AU - Jin, Wanqin

PY - 2017

Y1 - 2017

N2 - A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of l-/d-alanine and Zn(CH3COO)2·2H2O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP d-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.

AB - A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of l-/d-alanine and Zn(CH3COO)2·2H2O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP d-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.

UR - http://www.scopus.com/inward/record.url?scp=85021776735&partnerID=8YFLogxK

U2 - 10.1039/c7ce00522a

DO - 10.1039/c7ce00522a

M3 - 文章

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SN - 1466-8033

VL - 19

SP - 2718

EP - 2722

JO - CrystEngComm

JF - CrystEngComm

IS - 20

ER -

Homochiral porous coordination polymers with a rare utk topology and two types of uniform channels for enantioseparation

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