Hot-air aging failure mechanisms of carbonyl iron powder/methyl vinyl silicone rubber microwave-absorbing materials

Yuhong Zhang, Jingfeng Xu, Yongbao Feng, Tai Qiu

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A rubber microwave-absorbing material was prepared by compounding methyl vinyl silicone rubber (VMQ) and 45 vol% carbonyl iron powder (CIP). When used in a high-temperature environment at long periods, the material undergoes thermal aging and rapid degradation. This work mainly aimed to investigate the thermal behavior and aging failure mechanisms of such material during hot-air aging at 200°C. The mechanical and electromagnetic properties were measured with an electronic tensile testing machine and a network analyzer, respectively. Results indicate that CIP was oxidized by oxygen in the aging process and produced reactive oxygen species, which catalyzed the cross-linking of VMQ. The increased cross-linking density changed the mechanical properties and enhanced the thermal stability of the CIP/VMQ composite-absorbing material. Thermal aging gradually penetrated the surface and proceeded into the interior of the material. The microwave-absorbing properties deteriorated after hot-air aging.

Original languageEnglish
Pages (from-to)3262-3275
Number of pages14
JournalAdvances in Polymer Technology
Volume37
Issue number8
DOIs
StatePublished - Dec 2018

Keywords

  • carbonyl iron powder
  • hot-air aging
  • methyl vinyl silicone rubber
  • microwave absorption

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