How pore hydrophilicity influences water permeability?

Membrane separation is playing increasingly important role in providing clean water. Simulations predict that membrane pores with strong hydrophobicity produce ultrahigh water permeability as a result of low friction. However, experiments demonstrate that hydrophilic pores favor higher permeability. Herein we simulate water molecules transporting through interlayers of twodimensional nanosheets with various hydrophilicities using nonequilibriummolecular dynamics.We reveal that there is a threshold pressure drop (ΔP_T), exceeding which stable water permeability appears. Strongly hydrophobic pores exhibit extremely high ΔP_T, prohibiting the achievement of ultrahigh water permeability under the experimentally accessible pressures. Under pressures < ΔP_T, water flows in hydrophobic pores in a running-stop mode because of alternative wetting and nonwetting, thus leading to significantly reduced permeability.We discover that hydrophilicmodification to one surface of the nanosheet can remarkably reduce ΔP_T by > 99%, indicating a promising strategy to experimentally realize ultrafast membranes.