TY - JOUR
T1 - H3(CH2)6NH3][P 2v5O17·3.83H2O
T2 - A new 3D organic-templated vanadophosphate with extra-large 16-membered ring constructed from nanosized P-O-V wheels
AU - Zhang, Zhibin
AU - Xu, Yan
AU - Zheng, Lei
AU - Zhu, Dunru
PY - 2010/8
Y1 - 2010/8
N2 - A new porous 3D vanadophosphate, [NH3(CH2) 6NH3][P2V5O17]·3. 83H2O (1) is synthesized by using NH2(CH2) 6NH2 as template, and characterized by single crystal, structural analysis, X-ray diffraction, IR spectroscopy, TG analysis, and powder XRD. Single crystal analysis shows that compound 1 crystallizes in cubic shape, space group Im3̄m with cell dimensions: a = b = c = 26.5068(8) Å, V = 1.8624.0(1.0) Å3, Z = 24. Structural refinement indicates that the inorganic framework of 1 is constructed from nanosized P-O-V wheels.
AB - A new porous 3D vanadophosphate, [NH3(CH2) 6NH3][P2V5O17]·3. 83H2O (1) is synthesized by using NH2(CH2) 6NH2 as template, and characterized by single crystal, structural analysis, X-ray diffraction, IR spectroscopy, TG analysis, and powder XRD. Single crystal analysis shows that compound 1 crystallizes in cubic shape, space group Im3̄m with cell dimensions: a = b = c = 26.5068(8) Å, V = 1.8624.0(1.0) Å3, Z = 24. Structural refinement indicates that the inorganic framework of 1 is constructed from nanosized P-O-V wheels.
KW - Crystal structure
KW - Solvothermal synthesis
KW - Vanadophosphate
UR - http://www.scopus.com/inward/record.url?scp=77955438313&partnerID=8YFLogxK
U2 - 10.1002/zaac.200900467
DO - 10.1002/zaac.200900467
M3 - 文章
AN - SCOPUS:77955438313
SN - 0044-2313
VL - 636
SP - 1576
EP - 1579
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 8
ER -