Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts

A. A. Strekalova; A. A. Shesterkina; E. V. Shuvalova; C. R.D. Correia; Boqing Xu; Xuezhi Duan; Yanhui Yang; L. M. Kustov

doi:10.1134/S1070428022050128

Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts

A. A. Strekalova, A. A. Shesterkina, E. V. Shuvalova, C. R.D. Correia, Boqing Xu, Xuezhi Duan, Yanhui Yang, L. M. Kustov

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Abstract: The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu–1%Pt/SiO₂ catalyst with a full ester conversion in 6 h of the reaction.

Original language	English
Pages (from-to)	720-723
Number of pages	4
Journal	Russian Journal of Organic Chemistry
Volume	58
Issue number	5
DOIs	https://doi.org/10.1134/S1070428022050128
State	Published - May 2022

Keywords

3-methylbut-3-en-1-yl acetate
copper-platinum bimetallic catalyst
hydrogenation
isoprenol

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10.1134/S1070428022050128

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title = "Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts",

abstract = "Abstract: The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu–1%Pt/SiO2 catalyst with a full ester conversion in 6 h of the reaction.",

keywords = "3-methylbut-3-en-1-yl acetate, copper-platinum bimetallic catalyst, hydrogenation, isoprenol",

author = "Strekalova, {A. A.} and Shesterkina, {A. A.} and Shuvalova, {E. V.} and Correia, {C. R.D.} and Boqing Xu and Xuezhi Duan and Yanhui Yang and Kustov, {L. M.}",

note = "Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = may,

doi = "10.1134/S1070428022050128",

language = "英语",

volume = "58",

pages = "720--723",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "Pleiades Publishing",

number = "5",

}

TY - JOUR

T1 - Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts

AU - Strekalova, A. A.

AU - Shesterkina, A. A.

AU - Shuvalova, E. V.

AU - Correia, C. R.D.

AU - Xu, Boqing

AU - Duan, Xuezhi

AU - Yang, Yanhui

AU - Kustov, L. M.

PY - 2022/5

Y1 - 2022/5

N2 - Abstract: The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu–1%Pt/SiO2 catalyst with a full ester conversion in 6 h of the reaction.

AB - Abstract: The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu–1%Pt/SiO2 catalyst with a full ester conversion in 6 h of the reaction.

KW - 3-methylbut-3-en-1-yl acetate

KW - copper-platinum bimetallic catalyst

KW - hydrogenation

KW - isoprenol

UR - http://www.scopus.com/inward/record.url?scp=85133014982&partnerID=8YFLogxK

U2 - 10.1134/S1070428022050128

DO - 10.1134/S1070428022050128

M3 - 文章

AN - SCOPUS:85133014982

SN - 1070-4280

VL - 58

SP - 720

EP - 723

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

IS - 5

ER -

Hydrogenation of 3-Methyl-3-buten-1-yl Acetate to Alcohols in the Presence of Bimetallic Cu˗Pt Catalysts

Abstract

Keywords

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