TY - JOUR
T1 - Hydrothermal synthesis and structure of a new three-dimensional inorganic-organic hybrid polyoxomolybdate based on keggin cluster units
AU - Chen, Qi
AU - Cai, Chunxiu
AU - Zhou, Guangpeng
AU - Xu, Yan
AU - Zhu, Dunru
AU - Zheng, Xuefang
PY - 2008/6
Y1 - 2008/6
N2 - A new 3-D inorganic-organic hybrid compound {[Cu(4,4′-bipy)] 3(4,4′-bipy)}[PMo12O40]·2H 2O (1) was hydrothermally synthesized and characterized by IR, TG and X-ray diffraction analysis. Single crystal X-ray diffraction confirms that this compound crystallizes in the triclinic crystal system, space group P-1 with a = 10.9180(11), b = 12.3759(13), c = 13.0264(13) Å, α = 113.3560(10)°, β = 93.8730(10)°, γ = 99.0300(10)°. V = 1579.4(3) A°3, Z = 1. Structural analysis indicates that compound 1 exhibits a three-dimensional structure, in which Keggin anions [PMo 12O40]3- are linked by infinite [Cu(4,4′-bipy)]+n chains through Cu-O, and come into being a 3-D inorganic-organic hybrid open framework. The guest 4,4′-bipy molecules and water molecules are filled in the channel formed by Keggin anions [PMo12O40]3- and [Cu(4,4′-bipy)] +n chains.
AB - A new 3-D inorganic-organic hybrid compound {[Cu(4,4′-bipy)] 3(4,4′-bipy)}[PMo12O40]·2H 2O (1) was hydrothermally synthesized and characterized by IR, TG and X-ray diffraction analysis. Single crystal X-ray diffraction confirms that this compound crystallizes in the triclinic crystal system, space group P-1 with a = 10.9180(11), b = 12.3759(13), c = 13.0264(13) Å, α = 113.3560(10)°, β = 93.8730(10)°, γ = 99.0300(10)°. V = 1579.4(3) A°3, Z = 1. Structural analysis indicates that compound 1 exhibits a three-dimensional structure, in which Keggin anions [PMo 12O40]3- are linked by infinite [Cu(4,4′-bipy)]+n chains through Cu-O, and come into being a 3-D inorganic-organic hybrid open framework. The guest 4,4′-bipy molecules and water molecules are filled in the channel formed by Keggin anions [PMo12O40]3- and [Cu(4,4′-bipy)] +n chains.
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Inorganic-organic hybrid compounds
KW - Polyoxomolybdates
UR - http://www.scopus.com/inward/record.url?scp=53849144648&partnerID=8YFLogxK
U2 - 10.1002/zaac.200800015
DO - 10.1002/zaac.200800015
M3 - 文章
AN - SCOPUS:53849144648
SN - 0044-2313
VL - 634
SP - 1197
EP - 1200
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 6-7
ER -