TY - JOUR
T1 - Hydrothermal synthesis, characterization, and luminescence of two new arsenic-vanadium compounds with a γ-[As8V14O 42(H2O)]4- anion
AU - Wang, Congling
AU - Zhou, Guangpeng
AU - Zhang, Zhibin
AU - Zhu, Dunru
AU - Xu, Yan
PY - 2011/4/10
Y1 - 2011/4/10
N2 - Two new compounds, [Zn(phen)3]2[γ-As 8V14O42(H2O)]·4H 2O (1) and [Cd(phen)3]2[γ-As 8V14O42(H2O)]·2H 2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrum, and thermogravimetric analysis. Compound 1 crystallizes in the triclinic space group P1 ̄ with a = 11.429(4) Å, b = 15.760(5) Å, c = 15.952(5) Å, α = 108.825(5)°, β = 92.194(5)°, γ = 104.155(5)°, V = 2615.6(15) Å3, Z = 1; 2 crystallizes in the triclinic space group P1̄ with a = 11.450(4) Å, b = 15.629(6) Å, c = 16.302(6) Å, α = 109.177(5)°, β = 92.628(5)°, γ = 104.251(4)°, V = 2644.8(17) Å3, Z = 1. Single-crystal structural analysis shows that both 1 and 2 consist of a new type of [γ-As8V 14O42(H2O)]4- cluster anion.
AB - Two new compounds, [Zn(phen)3]2[γ-As 8V14O42(H2O)]·4H 2O (1) and [Cd(phen)3]2[γ-As 8V14O42(H2O)]·2H 2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrum, and thermogravimetric analysis. Compound 1 crystallizes in the triclinic space group P1 ̄ with a = 11.429(4) Å, b = 15.760(5) Å, c = 15.952(5) Å, α = 108.825(5)°, β = 92.194(5)°, γ = 104.155(5)°, V = 2615.6(15) Å3, Z = 1; 2 crystallizes in the triclinic space group P1̄ with a = 11.450(4) Å, b = 15.629(6) Å, c = 16.302(6) Å, α = 109.177(5)°, β = 92.628(5)°, γ = 104.251(4)°, V = 2644.8(17) Å3, Z = 1. Single-crystal structural analysis shows that both 1 and 2 consist of a new type of [γ-As8V 14O42(H2O)]4- cluster anion.
KW - Arsenic-vanadate
KW - Crystal structure
KW - Hydrothermal synthesis
KW - [γ-AsVO(H O)]
UR - http://www.scopus.com/inward/record.url?scp=79953824738&partnerID=8YFLogxK
U2 - 10.1080/00958972.2011.565056
DO - 10.1080/00958972.2011.565056
M3 - 文章
AN - SCOPUS:79953824738
SN - 0095-8972
VL - 64
SP - 1198
EP - 1206
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 7
ER -