Hydrothermal synthesis, crystal structure and photoluminescent property of 2D layer coordination polymer [Cd(mbix)(BIPA)]

Hong Chen; Heng Xu; Guang Xiang Liu; Xiao Ming Ren

Hydrothermal synthesis, crystal structure and photoluminescent property of 2D layer coordination polymer [Cd(mbix)(BIPA)]

Hong Chen, Heng Xu, Guang Xiang Liu, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A 2D coordination polymer of [Cd(mbix)(BIPA)] (1) (H ₂BIPA=5- bromoisophthalic acid and mbix=1,3- bis(imidazol-1-ylmelhyl) benzene) has been hydrothermal prepared and characterized by elemental analysis, IR spcctroscopy and single-crystal X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2 ₁/n with a=1.0020(4) nm, b = 1.7544(7) nm, c = 1.208 8(5) nm, β=94.271(5), V =2.119 1(15) nm ³, D _C=1.861 g·cm ^-3, Z= 4, F(000)=1168, Goof= 1.085, R ₁=0.045 0, wR ₂=0.093 1. The crystal structure shows that the Cd ₂ units are formed by the two caroboxylate group adopting tridentate-chelating-bridging coordination mode, which are linked to form a 2D layer structure by the ligands, and further extended into a 3D supramolecular structure through C-H···O hydrogen bonding interactions and π-π weak interactions. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 710801.

Original language	English
Pages (from-to)	1508-1512
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	25
Issue number	8
State	Published - Aug 2009
Externally published	Yes

Keywords

5-bromoisophthalic acid: crystal structure
Cadmium complex
Photoluminescence

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@article{4eb1161d3e344cb6abf55b05f571226a,

title = "Hydrothermal synthesis, crystal structure and photoluminescent property of 2D layer coordination polymer [Cd(mbix)(BIPA)]",

abstract = "A 2D coordination polymer of [Cd(mbix)(BIPA)] (1) (H 2BIPA=5- bromoisophthalic acid and mbix=1,3- bis(imidazol-1-ylmelhyl) benzene) has been hydrothermal prepared and characterized by elemental analysis, IR spcctroscopy and single-crystal X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2 1/n with a=1.0020(4) nm, b = 1.7544(7) nm, c = 1.208 8(5) nm, β=94.271(5), V =2.119 1(15) nm 3, D C=1.861 g·cm -3, Z= 4, F(000)=1168, Goof= 1.085, R 1=0.045 0, wR 2=0.093 1. The crystal structure shows that the Cd 2 units are formed by the two caroboxylate group adopting tridentate-chelating-bridging coordination mode, which are linked to form a 2D layer structure by the ligands, and further extended into a 3D supramolecular structure through C-H···O hydrogen bonding interactions and π-π weak interactions. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 710801.",

keywords = "5-bromoisophthalic acid: crystal structure, Cadmium complex, Photoluminescence",

author = "Hong Chen and Heng Xu and Liu, {Guang Xiang} and Ren, {Xiao Ming}",

year = "2009",

month = aug,

language = "英语",

volume = "25",

pages = "1508--1512",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "8",

}

TY - JOUR

T1 - Hydrothermal synthesis, crystal structure and photoluminescent property of 2D layer coordination polymer [Cd(mbix)(BIPA)]

AU - Chen, Hong

AU - Xu, Heng

AU - Liu, Guang Xiang

AU - Ren, Xiao Ming

PY - 2009/8

Y1 - 2009/8

N2 - A 2D coordination polymer of [Cd(mbix)(BIPA)] (1) (H 2BIPA=5- bromoisophthalic acid and mbix=1,3- bis(imidazol-1-ylmelhyl) benzene) has been hydrothermal prepared and characterized by elemental analysis, IR spcctroscopy and single-crystal X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2 1/n with a=1.0020(4) nm, b = 1.7544(7) nm, c = 1.208 8(5) nm, β=94.271(5), V =2.119 1(15) nm 3, D C=1.861 g·cm -3, Z= 4, F(000)=1168, Goof= 1.085, R 1=0.045 0, wR 2=0.093 1. The crystal structure shows that the Cd 2 units are formed by the two caroboxylate group adopting tridentate-chelating-bridging coordination mode, which are linked to form a 2D layer structure by the ligands, and further extended into a 3D supramolecular structure through C-H···O hydrogen bonding interactions and π-π weak interactions. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 710801.

AB - A 2D coordination polymer of [Cd(mbix)(BIPA)] (1) (H 2BIPA=5- bromoisophthalic acid and mbix=1,3- bis(imidazol-1-ylmelhyl) benzene) has been hydrothermal prepared and characterized by elemental analysis, IR spcctroscopy and single-crystal X-ray diffraction structure analysis. The crystal is of monoclinic, space group P2 1/n with a=1.0020(4) nm, b = 1.7544(7) nm, c = 1.208 8(5) nm, β=94.271(5), V =2.119 1(15) nm 3, D C=1.861 g·cm -3, Z= 4, F(000)=1168, Goof= 1.085, R 1=0.045 0, wR 2=0.093 1. The crystal structure shows that the Cd 2 units are formed by the two caroboxylate group adopting tridentate-chelating-bridging coordination mode, which are linked to form a 2D layer structure by the ligands, and further extended into a 3D supramolecular structure through C-H···O hydrogen bonding interactions and π-π weak interactions. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 710801.

KW - 5-bromoisophthalic acid: crystal structure

KW - Cadmium complex

KW - Photoluminescence

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M3 - 文章

AN - SCOPUS:70349138509

SN - 1001-4861

VL - 25

SP - 1508

EP - 1512

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 8

ER -

Hydrothermal synthesis, crystal structure and photoluminescent property of 2D layer coordination polymer [Cd(mbix)(BIPA)]

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