TY - JOUR
T1 - In-situ thermally induced formation of an ultra-glossy hydrophilic surface for oil fouling prevention in TiO2@MXene membranes
AU - Sun, Yuqing
AU - Dai, Chenye
AU - Lu, Jian
AU - Zhu, Yapeng
AU - Deng, Yingxuan
AU - Cai, Xianyin
AU - Zou, Dong
AU - Jing, Wenheng
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2025/6/22
Y1 - 2025/6/22
N2 - Oil droplets are inevitably deposited on the surface of membranes, resulting in membrane contamination during oily sewage separation. To effectively prevent oil fouling, a TiO2@MXene membrane with an ultra-glossy hydrophilic surface was designed via in-situ thermal induction to regulate the membrane surface structure and properties. Through high temperature-induced evolving the Ti valence and the functional groups of Ti3C2Tx, uniform TiO2 nanoparticles were generated in-situ on the Ti3C2Tx surface while altering the surface structure and properties, which considerably improved the hydrophilicity, underwater oleophobic properties, and surface finish of the membrane. Specifically, the TiO2@MXene membrane (MT600) exhibited a low water contact angle of 7.5° and a high underwater oil contact angle of 133.3°. Notably, the oil adhesion force of the membrane was as low as 0.0013 μN, outperforming most oil water separation membranes. Thus, the unique structure and surface properties endowed MT600 membrane with excellent oil retention (TOC removal efficiency of > 95 %) and antipollution ability (permeance decay rates of < 10 %) for oil-in-water emulsion separation. This is because the ultra-glossy hydrophilic and oleophobic surface prompted the formation of a continuous and stable hydration layer on the membrane surface and prevented oil droplets from falling into the membrane grooves. Benefiting from the robust, ultra-glossy surface, the MT600 membrane exhibited excellent long-term durability and reusability (emulsion permeance recovery of > 90 %) in high-salt, highly acidic, and highly alkaline environments. This study opens pathways to realize ultra-glossy membrane surface for the efficient demulsification of small size emulsions and long-lasting, stable oil water separation.
AB - Oil droplets are inevitably deposited on the surface of membranes, resulting in membrane contamination during oily sewage separation. To effectively prevent oil fouling, a TiO2@MXene membrane with an ultra-glossy hydrophilic surface was designed via in-situ thermal induction to regulate the membrane surface structure and properties. Through high temperature-induced evolving the Ti valence and the functional groups of Ti3C2Tx, uniform TiO2 nanoparticles were generated in-situ on the Ti3C2Tx surface while altering the surface structure and properties, which considerably improved the hydrophilicity, underwater oleophobic properties, and surface finish of the membrane. Specifically, the TiO2@MXene membrane (MT600) exhibited a low water contact angle of 7.5° and a high underwater oil contact angle of 133.3°. Notably, the oil adhesion force of the membrane was as low as 0.0013 μN, outperforming most oil water separation membranes. Thus, the unique structure and surface properties endowed MT600 membrane with excellent oil retention (TOC removal efficiency of > 95 %) and antipollution ability (permeance decay rates of < 10 %) for oil-in-water emulsion separation. This is because the ultra-glossy hydrophilic and oleophobic surface prompted the formation of a continuous and stable hydration layer on the membrane surface and prevented oil droplets from falling into the membrane grooves. Benefiting from the robust, ultra-glossy surface, the MT600 membrane exhibited excellent long-term durability and reusability (emulsion permeance recovery of > 90 %) in high-salt, highly acidic, and highly alkaline environments. This study opens pathways to realize ultra-glossy membrane surface for the efficient demulsification of small size emulsions and long-lasting, stable oil water separation.
KW - Oil fouling prevention
KW - Oil water separation
KW - robust TiO@MXene membrane
KW - Ultra-glossy hydrophilic surface
UR - http://www.scopus.com/inward/record.url?scp=85209881376&partnerID=8YFLogxK
U2 - 10.1016/j.seppur.2024.130599
DO - 10.1016/j.seppur.2024.130599
M3 - 文章
AN - SCOPUS:85209881376
SN - 1383-5866
VL - 359
JO - Separation and Purification Technology
JF - Separation and Purification Technology
M1 - 130599
ER -