InCl3-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies

Jun Lu; Shun Jun Ji; Rong Qian; Jian Ping Chen; Yu Liu; Teck Peng Loh

doi:10.1055/s-2004-815433

InCl₃-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies

Jun Lu, Shun Jun Ji, Rong Qian, Jian Ping Chen, Yu Liu, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

Original language	English
Pages (from-to)	534-536
Number of pages	3
Journal	Synlett
Issue number	3
DOIs	https://doi.org/10.1055/s-2004-815433
State	Published - 18 Feb 2004
Externally published	Yes

Keywords

Aldehydes
Allylation
Catalyst
Indium trichloride
Ionic liquid

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10.1055/s-2004-815433

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title = "InCl3-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies",

abstract = "Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.",

keywords = "Aldehydes, Allylation, Catalyst, Indium trichloride, Ionic liquid",

author = "Jun Lu and Ji, {Shun Jun} and Rong Qian and Chen, {Jian Ping} and Yu Liu and Loh, {Teck Peng}",

year = "2004",

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T1 - InCl3-Promoted Allylation of Aldehydes in Ionic Liquid

T2 - Scope and Enantioselectivity Studies

AU - Lu, Jun

AU - Ji, Shun Jun

AU - Qian, Rong

AU - Chen, Jian Ping

AU - Liu, Yu

AU - Loh, Teck Peng

PY - 2004/2/18

Y1 - 2004/2/18

N2 - Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

AB - Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.

KW - Aldehydes

KW - Allylation

KW - Catalyst

KW - Indium trichloride

KW - Ionic liquid

UR - http://www.scopus.com/inward/record.url?scp=1442286554&partnerID=8YFLogxK

U2 - 10.1055/s-2004-815433

DO - 10.1055/s-2004-815433

M3 - 文章

AN - SCOPUS:1442286554

SN - 0936-5214

SP - 534

EP - 536

JO - Synlett

JF - Synlett

IS - 3

ER -

InCl₃-Promoted Allylation of Aldehydes in Ionic Liquid: Scope and Enantioselectivity Studies

Abstract

Keywords

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