TY - JOUR
T1 - Insights into the Catalytic Performance of Multichannel Ceramic Catalytic Membrane in Liquid-Phase p-Nitrophenol Hydrogenation
T2 - Role of Storage Method
AU - Guo, Zhihao
AU - Chen, Ziming
AU - Zhang, Jiuxuan
AU - Tang, Zhenchen
AU - Jiang, Hong
AU - Chen, Rizhi
N1 - Publisher Copyright:
© 2024 American Chemical Society.
PY - 2024/7/17
Y1 - 2024/7/17
N2 - Catalytic membrane reactor is an improving approach for the green chemical industry. The highly efficient storage method of a catalytic membrane is vital for maintaining its catalytic performance. Herein, a simple and efficient storage method was developed for the Co@CM multichannel ceramic catalytic membrane, i.e., storing the fresh catalytic membrane in ethanol before use. The yielded Co@CM-E-W has the smallest contact angle with the reaction solvent and the shortest penetration time for the solvent into the membrane pores, which can promote the reaction solution into the membrane pores and suppress the leaching of Co nanoparticles, thereby enhancing its catalytic activity and stability. Co@CM-E-W achieves 100% conversion of p-nitrophenol within 20 min in each reaction cycle.
AB - Catalytic membrane reactor is an improving approach for the green chemical industry. The highly efficient storage method of a catalytic membrane is vital for maintaining its catalytic performance. Herein, a simple and efficient storage method was developed for the Co@CM multichannel ceramic catalytic membrane, i.e., storing the fresh catalytic membrane in ethanol before use. The yielded Co@CM-E-W has the smallest contact angle with the reaction solvent and the shortest penetration time for the solvent into the membrane pores, which can promote the reaction solution into the membrane pores and suppress the leaching of Co nanoparticles, thereby enhancing its catalytic activity and stability. Co@CM-E-W achieves 100% conversion of p-nitrophenol within 20 min in each reaction cycle.
UR - http://www.scopus.com/inward/record.url?scp=85198166635&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.4c01433
DO - 10.1021/acs.iecr.4c01433
M3 - 文章
AN - SCOPUS:85198166635
SN - 0888-5885
VL - 63
SP - 12715
EP - 12719
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
IS - 28
ER -